Cargando…

Diacetato-κO;κ(2) O,O′-aqua­(2,4,6-tri-2-pyridyl-1,3,5-triazine-κ(3) N (2),N (1),N (6))manganese(II) monohydrate

The Mn(II) ion in the title compound, [Mn(CH(3)CO(2))(2)(C(18)H(12)N(6))(H(2)O)]·H(2)O, is seven-coordinated in an approximately penta­gonal–bipyramidal geometry by three N atoms of the tridentate 2,4,6-tri-2-pyridyl-1,3,5-triazine ligand and four O atoms from two distinct anionic acetato ligands an...

Descripción completa

Detalles Bibliográficos
Autor principal: Ha, Kwang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200744/
https://www.ncbi.nlm.nih.gov/pubmed/22058860
http://dx.doi.org/10.1107/S1600536811032016
_version_ 1782214739720404992
author Ha, Kwang
author_facet Ha, Kwang
author_sort Ha, Kwang
collection PubMed
description The Mn(II) ion in the title compound, [Mn(CH(3)CO(2))(2)(C(18)H(12)N(6))(H(2)O)]·H(2)O, is seven-coordinated in an approximately penta­gonal–bipyramidal geometry by three N atoms of the tridentate 2,4,6-tri-2-pyridyl-1,3,5-triazine ligand and four O atoms from two distinct anionic acetato ligands and a water mol­ecule. One acetate anion chelates the Mn atom via two O atoms occupying equatorial positions, and the other anion coordinates the Mn atom as a monodentate ligand via one O atom. The complex and solvent water mol­ecules are linked by inter- and intra­molecular O—H⋯O, O—H⋯N and C—H⋯O hydrogen bonds into a three-dimensional network.
format Online
Article
Text
id pubmed-3200744
institution National Center for Biotechnology Information
language English
publishDate 2011
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-32007442011-11-06 Diacetato-κO;κ(2) O,O′-aqua­(2,4,6-tri-2-pyridyl-1,3,5-triazine-κ(3) N (2),N (1),N (6))manganese(II) monohydrate Ha, Kwang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Mn(II) ion in the title compound, [Mn(CH(3)CO(2))(2)(C(18)H(12)N(6))(H(2)O)]·H(2)O, is seven-coordinated in an approximately penta­gonal–bipyramidal geometry by three N atoms of the tridentate 2,4,6-tri-2-pyridyl-1,3,5-triazine ligand and four O atoms from two distinct anionic acetato ligands and a water mol­ecule. One acetate anion chelates the Mn atom via two O atoms occupying equatorial positions, and the other anion coordinates the Mn atom as a monodentate ligand via one O atom. The complex and solvent water mol­ecules are linked by inter- and intra­molecular O—H⋯O, O—H⋯N and C—H⋯O hydrogen bonds into a three-dimensional network. International Union of Crystallography 2011-08-17 /pmc/articles/PMC3200744/ /pubmed/22058860 http://dx.doi.org/10.1107/S1600536811032016 Text en © Kwang Ha 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Ha, Kwang
Diacetato-κO;κ(2) O,O′-aqua­(2,4,6-tri-2-pyridyl-1,3,5-triazine-κ(3) N (2),N (1),N (6))manganese(II) monohydrate
title Diacetato-κO;κ(2) O,O′-aqua­(2,4,6-tri-2-pyridyl-1,3,5-triazine-κ(3) N (2),N (1),N (6))manganese(II) monohydrate
title_full Diacetato-κO;κ(2) O,O′-aqua­(2,4,6-tri-2-pyridyl-1,3,5-triazine-κ(3) N (2),N (1),N (6))manganese(II) monohydrate
title_fullStr Diacetato-κO;κ(2) O,O′-aqua­(2,4,6-tri-2-pyridyl-1,3,5-triazine-κ(3) N (2),N (1),N (6))manganese(II) monohydrate
title_full_unstemmed Diacetato-κO;κ(2) O,O′-aqua­(2,4,6-tri-2-pyridyl-1,3,5-triazine-κ(3) N (2),N (1),N (6))manganese(II) monohydrate
title_short Diacetato-κO;κ(2) O,O′-aqua­(2,4,6-tri-2-pyridyl-1,3,5-triazine-κ(3) N (2),N (1),N (6))manganese(II) monohydrate
title_sort diacetato-κo;κ(2) o,o′-aqua­(2,4,6-tri-2-pyridyl-1,3,5-triazine-κ(3) n (2),n (1),n (6))manganese(ii) monohydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200744/
https://www.ncbi.nlm.nih.gov/pubmed/22058860
http://dx.doi.org/10.1107/S1600536811032016
work_keys_str_mv AT hakwang diacetatokok2ooaqua246tri2pyridyl135triazinek3n2n1n6manganeseiimonohydrate