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Diacetato-κO;κ(2) O,O′-aqua(2,4,6-tri-2-pyridyl-1,3,5-triazine-κ(3) N (2),N (1),N (6))manganese(II) monohydrate
The Mn(II) ion in the title compound, [Mn(CH(3)CO(2))(2)(C(18)H(12)N(6))(H(2)O)]·H(2)O, is seven-coordinated in an approximately pentagonal–bipyramidal geometry by three N atoms of the tridentate 2,4,6-tri-2-pyridyl-1,3,5-triazine ligand and four O atoms from two distinct anionic acetato ligands an...
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200744/ https://www.ncbi.nlm.nih.gov/pubmed/22058860 http://dx.doi.org/10.1107/S1600536811032016 |
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author | Ha, Kwang |
author_facet | Ha, Kwang |
author_sort | Ha, Kwang |
collection | PubMed |
description | The Mn(II) ion in the title compound, [Mn(CH(3)CO(2))(2)(C(18)H(12)N(6))(H(2)O)]·H(2)O, is seven-coordinated in an approximately pentagonal–bipyramidal geometry by three N atoms of the tridentate 2,4,6-tri-2-pyridyl-1,3,5-triazine ligand and four O atoms from two distinct anionic acetato ligands and a water molecule. One acetate anion chelates the Mn atom via two O atoms occupying equatorial positions, and the other anion coordinates the Mn atom as a monodentate ligand via one O atom. The complex and solvent water molecules are linked by inter- and intramolecular O—H⋯O, O—H⋯N and C—H⋯O hydrogen bonds into a three-dimensional network. |
format | Online Article Text |
id | pubmed-3200744 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32007442011-11-06 Diacetato-κO;κ(2) O,O′-aqua(2,4,6-tri-2-pyridyl-1,3,5-triazine-κ(3) N (2),N (1),N (6))manganese(II) monohydrate Ha, Kwang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Mn(II) ion in the title compound, [Mn(CH(3)CO(2))(2)(C(18)H(12)N(6))(H(2)O)]·H(2)O, is seven-coordinated in an approximately pentagonal–bipyramidal geometry by three N atoms of the tridentate 2,4,6-tri-2-pyridyl-1,3,5-triazine ligand and four O atoms from two distinct anionic acetato ligands and a water molecule. One acetate anion chelates the Mn atom via two O atoms occupying equatorial positions, and the other anion coordinates the Mn atom as a monodentate ligand via one O atom. The complex and solvent water molecules are linked by inter- and intramolecular O—H⋯O, O—H⋯N and C—H⋯O hydrogen bonds into a three-dimensional network. International Union of Crystallography 2011-08-17 /pmc/articles/PMC3200744/ /pubmed/22058860 http://dx.doi.org/10.1107/S1600536811032016 Text en © Kwang Ha 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Ha, Kwang Diacetato-κO;κ(2) O,O′-aqua(2,4,6-tri-2-pyridyl-1,3,5-triazine-κ(3) N (2),N (1),N (6))manganese(II) monohydrate |
title | Diacetato-κO;κ(2)
O,O′-aqua(2,4,6-tri-2-pyridyl-1,3,5-triazine-κ(3)
N
(2),N
(1),N
(6))manganese(II) monohydrate |
title_full | Diacetato-κO;κ(2)
O,O′-aqua(2,4,6-tri-2-pyridyl-1,3,5-triazine-κ(3)
N
(2),N
(1),N
(6))manganese(II) monohydrate |
title_fullStr | Diacetato-κO;κ(2)
O,O′-aqua(2,4,6-tri-2-pyridyl-1,3,5-triazine-κ(3)
N
(2),N
(1),N
(6))manganese(II) monohydrate |
title_full_unstemmed | Diacetato-κO;κ(2)
O,O′-aqua(2,4,6-tri-2-pyridyl-1,3,5-triazine-κ(3)
N
(2),N
(1),N
(6))manganese(II) monohydrate |
title_short | Diacetato-κO;κ(2)
O,O′-aqua(2,4,6-tri-2-pyridyl-1,3,5-triazine-κ(3)
N
(2),N
(1),N
(6))manganese(II) monohydrate |
title_sort | diacetato-κo;κ(2)
o,o′-aqua(2,4,6-tri-2-pyridyl-1,3,5-triazine-κ(3)
n
(2),n
(1),n
(6))manganese(ii) monohydrate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200744/ https://www.ncbi.nlm.nih.gov/pubmed/22058860 http://dx.doi.org/10.1107/S1600536811032016 |
work_keys_str_mv | AT hakwang diacetatokok2ooaqua246tri2pyridyl135triazinek3n2n1n6manganeseiimonohydrate |