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3,3,4,4-Tetra­fluoro-1-[2-(3,3,4,4-tetra­fluoro­pyrrolidin-1-yl)phen­yl]pyrrolidine

The asymmetric unit of the title compound, C(14)H(12)F(8)N(2), contains one tetra­fluoro­pyrrolidine system and one half-mol­ecule of benzene; the latter, together with a second heterocyclic unit, are completed by symmetry, with a twofold crystallographic axis crossing through both the middle of the...

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Detalles Bibliográficos
Autores principales: Wang, Jin, Zhong, Jun-Wen, Liu, Pei-Lian, Cao, Wan-Wan, Zeng, Zhuo
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200749/
https://www.ncbi.nlm.nih.gov/pubmed/22065017
http://dx.doi.org/10.1107/S1600536811033757
Descripción
Sumario:The asymmetric unit of the title compound, C(14)H(12)F(8)N(2), contains one tetra­fluoro­pyrrolidine system and one half-mol­ecule of benzene; the latter, together with a second heterocyclic unit, are completed by symmetry, with a twofold crystallographic axis crossing through both the middle of the bond between the C atoms bearing the heterocyclic rings and the opposite C—C bonds of the whole benzene mol­ecule. The pyrrolidine ring shows an envelope conformation with the apex at the N atom. The dihedral angle between the least-squares plane of this ring and the benzene ring is 36.9 (5)°. There are intra­molecular C—H⋯N inter­actions generating S(6) ring motifs. In the crystal structure, the mol­ecules are linked by C—H⋯F inter­actions, forming chains parallel to [010].