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cis-[1,2-Bis(diphenylarsanyl)ethane-κ(2) As,As’]tetracarbonylchromium(0)
In the title compound, [Cr(C(26)H(24)As(2))(CO)(4)], the Cr atom is octahedrally coordinated by four carbonyl ligands and one bidentate 1,2-bis(diphenylarsanyl)ethane ligand, which chelates in a cis manner with an As—Cr—As bite angle of 82.513 (9)°. The dihedral angles between the pairs of benze...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2011
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200751/ https://www.ncbi.nlm.nih.gov/pubmed/22065153 http://dx.doi.org/10.1107/S1600536811032314 |
| _version_ | 1782214741328920576 |
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| author | Norlidah, M. N. Azhar, M. Y. Bin Shawkataly, Omar Rosli, Mohd Mustaqim Fun, Hoong-Kun |
| author_facet | Norlidah, M. N. Azhar, M. Y. Bin Shawkataly, Omar Rosli, Mohd Mustaqim Fun, Hoong-Kun |
| author_sort | Norlidah, M. N. |
| collection | PubMed |
| description | In the title compound, [Cr(C(26)H(24)As(2))(CO)(4)], the Cr atom is octahedrally coordinated by four carbonyl ligands and one bidentate 1,2-bis(diphenylarsanyl)ethane ligand, which chelates in a cis manner with an As—Cr—As bite angle of 82.513 (9)°. The dihedral angles between the pairs of benzene rings attached to each As atom are 84.63 (9) and 77.15 (8)°. In the crystal, molecules are linked by C—H⋯O interactions, forming infinite chains along the a axis. The crystal structure is further stabilized by C—H⋯π interactions. |
| format | Online Article Text |
| id | pubmed-3200751 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-32007512011-11-06 cis-[1,2-Bis(diphenylarsanyl)ethane-κ(2) As,As’]tetracarbonylchromium(0) Norlidah, M. N. Azhar, M. Y. Bin Shawkataly, Omar Rosli, Mohd Mustaqim Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cr(C(26)H(24)As(2))(CO)(4)], the Cr atom is octahedrally coordinated by four carbonyl ligands and one bidentate 1,2-bis(diphenylarsanyl)ethane ligand, which chelates in a cis manner with an As—Cr—As bite angle of 82.513 (9)°. The dihedral angles between the pairs of benzene rings attached to each As atom are 84.63 (9) and 77.15 (8)°. In the crystal, molecules are linked by C—H⋯O interactions, forming infinite chains along the a axis. The crystal structure is further stabilized by C—H⋯π interactions. International Union of Crystallography 2011-08-27 /pmc/articles/PMC3200751/ /pubmed/22065153 http://dx.doi.org/10.1107/S1600536811032314 Text en © Norlidah et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Norlidah, M. N. Azhar, M. Y. Bin Shawkataly, Omar Rosli, Mohd Mustaqim Fun, Hoong-Kun cis-[1,2-Bis(diphenylarsanyl)ethane-κ(2) As,As’]tetracarbonylchromium(0) |
| title |
cis-[1,2-Bis(diphenylarsanyl)ethane-κ(2)
As,As’]tetracarbonylchromium(0) |
| title_full |
cis-[1,2-Bis(diphenylarsanyl)ethane-κ(2)
As,As’]tetracarbonylchromium(0) |
| title_fullStr |
cis-[1,2-Bis(diphenylarsanyl)ethane-κ(2)
As,As’]tetracarbonylchromium(0) |
| title_full_unstemmed |
cis-[1,2-Bis(diphenylarsanyl)ethane-κ(2)
As,As’]tetracarbonylchromium(0) |
| title_short |
cis-[1,2-Bis(diphenylarsanyl)ethane-κ(2)
As,As’]tetracarbonylchromium(0) |
| title_sort | cis-[1,2-bis(diphenylarsanyl)ethane-κ(2)
as,as’]tetracarbonylchromium(0) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200751/ https://www.ncbi.nlm.nih.gov/pubmed/22065153 http://dx.doi.org/10.1107/S1600536811032314 |
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