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1-[(E)-4-(Phenyldiazenyl)phenyl]-3-pyrroline-2,5-dione
The title compound, C(16)H(11)N(3)O(2), displays a trans configuration with respect to the azo group. The molecule is non-planar; the maleimide ring forms a dihedral angle of 42.35 (4)° with the benzene ring bonded to its N atom and the mean plane of this benzene ring is rotated by 21.46 (8)° with...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2011
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200752/ https://www.ncbi.nlm.nih.gov/pubmed/22065404 http://dx.doi.org/10.1107/S160053681103193X |
| Sumario: | The title compound, C(16)H(11)N(3)O(2), displays a trans configuration with respect to the azo group. The molecule is non-planar; the maleimide ring forms a dihedral angle of 42.35 (4)° with the benzene ring bonded to its N atom and the mean plane of this benzene ring is rotated by 21.46 (8)° with respect to the azo group mean plane, which, in turn, forms a dihedral angle of 24.48 (7)° with the ‘terminal’ benzene ring. Molecules in the crystal are π–π stacked along the [100] direction with a mean interplanar distance of 3.857 (1) Å. In addition, C—H⋯O interactions link them into double layers parallel to the ac plane. |
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