1-[(E)-4-(Phenyl­diazen­yl)phen­yl]-3-pyrroline-2,5-dione

The title compound, C(16)H(11)N(3)O(2), displays a trans configuration with respect to the azo group. The mol­ecule is non-planar; the maleimide ring forms a dihedral angle of 42.35 (4)° with the benzene ring bonded to its N atom and the mean plane of this benzene ring is rotated by 21.46 (8)° with...

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Detalles Bibliográficos
Autores principales: Rusu, Elena, Shova, Sergiu, Rusu, Gheorghe
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200752/
https://www.ncbi.nlm.nih.gov/pubmed/22065404
http://dx.doi.org/10.1107/S160053681103193X
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author Rusu, Elena
Shova, Sergiu
Rusu, Gheorghe
author_facet Rusu, Elena
Shova, Sergiu
Rusu, Gheorghe
author_sort Rusu, Elena
collection PubMed
description The title compound, C(16)H(11)N(3)O(2), displays a trans configuration with respect to the azo group. The mol­ecule is non-planar; the maleimide ring forms a dihedral angle of 42.35 (4)° with the benzene ring bonded to its N atom and the mean plane of this benzene ring is rotated by 21.46 (8)° with respect to the azo group mean plane, which, in turn, forms a dihedral angle of 24.48 (7)° with the ‘terminal’ benzene ring. Mol­ecules in the crystal are π–π stacked along the [100] direction with a mean inter­planar distance of 3.857 (1) Å. In addition, C—H⋯O inter­actions link them into double layers parallel to the ac plane.
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spelling pubmed-32007522011-11-06 1-[(E)-4-(Phenyl­diazen­yl)phen­yl]-3-pyrroline-2,5-dione Rusu, Elena Shova, Sergiu Rusu, Gheorghe Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(16)H(11)N(3)O(2), displays a trans configuration with respect to the azo group. The mol­ecule is non-planar; the maleimide ring forms a dihedral angle of 42.35 (4)° with the benzene ring bonded to its N atom and the mean plane of this benzene ring is rotated by 21.46 (8)° with respect to the azo group mean plane, which, in turn, forms a dihedral angle of 24.48 (7)° with the ‘terminal’ benzene ring. Mol­ecules in the crystal are π–π stacked along the [100] direction with a mean inter­planar distance of 3.857 (1) Å. In addition, C—H⋯O inter­actions link them into double layers parallel to the ac plane. International Union of Crystallography 2011-08-11 /pmc/articles/PMC3200752/ /pubmed/22065404 http://dx.doi.org/10.1107/S160053681103193X Text en © Rusu et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Rusu, Elena
Shova, Sergiu
Rusu, Gheorghe
1-[(E)-4-(Phenyl­diazen­yl)phen­yl]-3-pyrroline-2,5-dione
title 1-[(E)-4-(Phenyl­diazen­yl)phen­yl]-3-pyrroline-2,5-dione
title_full 1-[(E)-4-(Phenyl­diazen­yl)phen­yl]-3-pyrroline-2,5-dione
title_fullStr 1-[(E)-4-(Phenyl­diazen­yl)phen­yl]-3-pyrroline-2,5-dione
title_full_unstemmed 1-[(E)-4-(Phenyl­diazen­yl)phen­yl]-3-pyrroline-2,5-dione
title_short 1-[(E)-4-(Phenyl­diazen­yl)phen­yl]-3-pyrroline-2,5-dione
title_sort 1-[(e)-4-(phenyl­diazen­yl)phen­yl]-3-pyrroline-2,5-dione
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200752/
https://www.ncbi.nlm.nih.gov/pubmed/22065404
http://dx.doi.org/10.1107/S160053681103193X
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