rac-cis-Cyclo­hexane-1,2-dicarb­oxy­lic acid–isoquinoline (1/1)

In the crystal structure of the title mol­ecular adduct, C(9)H(7)N·C(8)H(12)O(4), the two species are ­linked through a carb­oxy­lic acid–isoquinoline O—H⋯N hydrogen bond. These mol­ecular pairs then inter-associate through the second acid group of the cis-cyclo­hexane-1,2-dicarb­oxy­lic acid molecu...

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Detalles Bibliográficos
Autores principales: Smith, Graham, Wermuth, Urs D.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200759/
https://www.ncbi.nlm.nih.gov/pubmed/22058919
http://dx.doi.org/10.1107/S1600536811030613
Descripción
Sumario:In the crystal structure of the title mol­ecular adduct, C(9)H(7)N·C(8)H(12)O(4), the two species are ­linked through a carb­oxy­lic acid–isoquinoline O—H⋯N hydrogen bond. These mol­ecular pairs then inter-associate through the second acid group of the cis-cyclo­hexane-1,2-dicarb­oxy­lic acid molecules, forming a classic centrosymmetric cyclic head-to-head carb­oxy­lic acid–carboxyl O—H⋯O hydrogen-bonding association [graph-set R (2) (2)(8)], giving a zero-dimensional (cluster) structure, consisting of two of each species.

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