Bis(μ(2)-pyridine-2-carboxamide oximato)bis­[(pyridine-2-carboxamide oxime)zinc] dinitrate

In the title dinuclear compound, [Zn(2)(C(6)H(6)N(3)O)(2)(C(6)H(7)N(3)O)(2)](NO(3))(2), the Zn(II) cation is N,N′-chelated by one pyridine-2-carboxamide oximate anion and one pyridine-2-carboxamide oxime mol­ecule, and is further bridged by an oxime O atom from the adjacent pyridine-2-carboxamide ox...

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Detalles Bibliográficos
Autores principales: Deng, Xiao-Hui, Ran, Jing-Wen
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200762/
https://www.ncbi.nlm.nih.gov/pubmed/22058897
http://dx.doi.org/10.1107/S1600536811034908
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author Deng, Xiao-Hui
Ran, Jing-Wen
author_facet Deng, Xiao-Hui
Ran, Jing-Wen
author_sort Deng, Xiao-Hui
collection PubMed
description In the title dinuclear compound, [Zn(2)(C(6)H(6)N(3)O)(2)(C(6)H(7)N(3)O)(2)](NO(3))(2), the Zn(II) cation is N,N′-chelated by one pyridine-2-carboxamide oximate anion and one pyridine-2-carboxamide oxime mol­ecule, and is further bridged by an oxime O atom from the adjacent pyridine-2-carboxamide oximate anion, forming a distorted trigonal bipyramidal coordination. Two pyridine-2-carboxamide oximate anions bridge two Zn(II) cations to form the centrosymmetric dinuclear mol­ecule. Extensive O—H⋯O, N—H⋯O and O—H⋯N hydrogen bonds are present in the crystal structure.
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spelling pubmed-32007622011-11-06 Bis(μ(2)-pyridine-2-carboxamide oximato)bis­[(pyridine-2-carboxamide oxime)zinc] dinitrate Deng, Xiao-Hui Ran, Jing-Wen Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title dinuclear compound, [Zn(2)(C(6)H(6)N(3)O)(2)(C(6)H(7)N(3)O)(2)](NO(3))(2), the Zn(II) cation is N,N′-chelated by one pyridine-2-carboxamide oximate anion and one pyridine-2-carboxamide oxime mol­ecule, and is further bridged by an oxime O atom from the adjacent pyridine-2-carboxamide oximate anion, forming a distorted trigonal bipyramidal coordination. Two pyridine-2-carboxamide oximate anions bridge two Zn(II) cations to form the centrosymmetric dinuclear mol­ecule. Extensive O—H⋯O, N—H⋯O and O—H⋯N hydrogen bonds are present in the crystal structure. International Union of Crystallography 2011-08-31 /pmc/articles/PMC3200762/ /pubmed/22058897 http://dx.doi.org/10.1107/S1600536811034908 Text en © Deng and Ran 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Deng, Xiao-Hui
Ran, Jing-Wen
Bis(μ(2)-pyridine-2-carboxamide oximato)bis­[(pyridine-2-carboxamide oxime)zinc] dinitrate
title Bis(μ(2)-pyridine-2-carboxamide oximato)bis­[(pyridine-2-carboxamide oxime)zinc] dinitrate
title_full Bis(μ(2)-pyridine-2-carboxamide oximato)bis­[(pyridine-2-carboxamide oxime)zinc] dinitrate
title_fullStr Bis(μ(2)-pyridine-2-carboxamide oximato)bis­[(pyridine-2-carboxamide oxime)zinc] dinitrate
title_full_unstemmed Bis(μ(2)-pyridine-2-carboxamide oximato)bis­[(pyridine-2-carboxamide oxime)zinc] dinitrate
title_short Bis(μ(2)-pyridine-2-carboxamide oximato)bis­[(pyridine-2-carboxamide oxime)zinc] dinitrate
title_sort bis(μ(2)-pyridine-2-carboxamide oximato)bis­[(pyridine-2-carboxamide oxime)zinc] dinitrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200762/
https://www.ncbi.nlm.nih.gov/pubmed/22058897
http://dx.doi.org/10.1107/S1600536811034908
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