Cargando…
Ethyl 5-((1E)-1-{(E)-2-[1-(4-ethoxycarbonyl-3-methyl-1,2-oxazol-5-yl)ethylidene]hydrazin-1-ylidene}ethyl)-3-methyl-1,2-oxazole-4-carboxylate
The complete molecule of the title compound, C(18)H(22)N(4)O(6), is generated by the application of a twofold axis of symmetry. Twists are evident in the molecule, i.e. between each —C=N—N group and the adjacent oxazole ring [dihedral angle = 46.08 (12) °] and between the latter and attached ester...
Autores principales: | , , , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200773/ https://www.ncbi.nlm.nih.gov/pubmed/22058944 http://dx.doi.org/10.1107/S1600536811032004 |
Sumario: | The complete molecule of the title compound, C(18)H(22)N(4)O(6), is generated by the application of a twofold axis of symmetry. Twists are evident in the molecule, i.e. between each —C=N—N group and the adjacent oxazole ring [dihedral angle = 46.08 (12) °] and between the latter and attached ester group [excluding the terminal methyl group; dihedral angle = 24.4 (7) °]. In the crystal, C—H⋯O and π–π [3.5990 (11) Å] contacts connect molecules into supramolecular arrays in the ac plane. These stack along the b axis, being connected by weak π–π [3.3903 (11) Å] interactions. |
---|