A second monoclinic polymorph of 1-benzyl-N-methyl-1H-pyrrole-2-carboxamide

In the title compound, C(13)H(14)N(2)O, the N(pyrrole)—C(H(2))—C—C torsion angle is −7.7 (3)° and the dihedral angle between the pyrrole and benzene rings is 83.6 (2)°. In the crystal, inter­molecular N—H⋯O hydrogen bonds link the mol­ecules into chains extending along the c axis. We have previously...

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Detalles Bibliográficos
Autores principales: Wang, Chang Jun, Zeng, Xiang Chao, Xu, Shi Hai
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200776/
https://www.ncbi.nlm.nih.gov/pubmed/22058905
http://dx.doi.org/10.1107/S1600536811030364
Descripción
Sumario:In the title compound, C(13)H(14)N(2)O, the N(pyrrole)—C(H(2))—C—C torsion angle is −7.7 (3)° and the dihedral angle between the pyrrole and benzene rings is 83.6 (2)°. In the crystal, inter­molecular N—H⋯O hydrogen bonds link the mol­ecules into chains extending along the c axis. We have previously reported another polymorphic form of this title compound, which has the same space group with different cell parameters: a = 9.8285 (18) Å, b = 23.588 (4) Å, c = 9.9230 (17) Å, β = 90.107 (3)°, Z = 8 and V = 2300.5 (7) Å(3) [Zeng et al. (2010 ▶). Acta Cryst. E66, o2051].

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