A second monoclinic polymorph of 1-benzyl-N-methyl-1H-pyrrole-2-carboxamide

In the title compound, C(13)H(14)N(2)O, the N(pyrrole)—C(H(2))—C—C torsion angle is −7.7 (3)° and the dihedral angle between the pyrrole and benzene rings is 83.6 (2)°. In the crystal, inter­molecular N—H⋯O hydrogen bonds link the mol­ecules into chains extending along the c axis. We have previously...

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Detalles Bibliográficos
Autores principales: Wang, Chang Jun, Zeng, Xiang Chao, Xu, Shi Hai
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200776/
https://www.ncbi.nlm.nih.gov/pubmed/22058905
http://dx.doi.org/10.1107/S1600536811030364
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author Wang, Chang Jun
Zeng, Xiang Chao
Xu, Shi Hai
author_facet Wang, Chang Jun
Zeng, Xiang Chao
Xu, Shi Hai
author_sort Wang, Chang Jun
collection PubMed
description In the title compound, C(13)H(14)N(2)O, the N(pyrrole)—C(H(2))—C—C torsion angle is −7.7 (3)° and the dihedral angle between the pyrrole and benzene rings is 83.6 (2)°. In the crystal, inter­molecular N—H⋯O hydrogen bonds link the mol­ecules into chains extending along the c axis. We have previously reported another polymorphic form of this title compound, which has the same space group with different cell parameters: a = 9.8285 (18) Å, b = 23.588 (4) Å, c = 9.9230 (17) Å, β = 90.107 (3)°, Z = 8 and V = 2300.5 (7) Å(3) [Zeng et al. (2010 ▶). Acta Cryst. E66, o2051].
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spelling pubmed-32007762011-11-06 A second monoclinic polymorph of 1-benzyl-N-methyl-1H-pyrrole-2-carboxamide Wang, Chang Jun Zeng, Xiang Chao Xu, Shi Hai Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(13)H(14)N(2)O, the N(pyrrole)—C(H(2))—C—C torsion angle is −7.7 (3)° and the dihedral angle between the pyrrole and benzene rings is 83.6 (2)°. In the crystal, inter­molecular N—H⋯O hydrogen bonds link the mol­ecules into chains extending along the c axis. We have previously reported another polymorphic form of this title compound, which has the same space group with different cell parameters: a = 9.8285 (18) Å, b = 23.588 (4) Å, c = 9.9230 (17) Å, β = 90.107 (3)°, Z = 8 and V = 2300.5 (7) Å(3) [Zeng et al. (2010 ▶). Acta Cryst. E66, o2051]. International Union of Crystallography 2011-08-02 /pmc/articles/PMC3200776/ /pubmed/22058905 http://dx.doi.org/10.1107/S1600536811030364 Text en © Wang et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Wang, Chang Jun
Zeng, Xiang Chao
Xu, Shi Hai
A second monoclinic polymorph of 1-benzyl-N-methyl-1H-pyrrole-2-carboxamide
title A second monoclinic polymorph of 1-benzyl-N-methyl-1H-pyrrole-2-carboxamide
title_full A second monoclinic polymorph of 1-benzyl-N-methyl-1H-pyrrole-2-carboxamide
title_fullStr A second monoclinic polymorph of 1-benzyl-N-methyl-1H-pyrrole-2-carboxamide
title_full_unstemmed A second monoclinic polymorph of 1-benzyl-N-methyl-1H-pyrrole-2-carboxamide
title_short A second monoclinic polymorph of 1-benzyl-N-methyl-1H-pyrrole-2-carboxamide
title_sort second monoclinic polymorph of 1-benzyl-n-methyl-1h-pyrrole-2-carboxamide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200776/
https://www.ncbi.nlm.nih.gov/pubmed/22058905
http://dx.doi.org/10.1107/S1600536811030364
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