2-Chloro-N-[2-(2-fluoro­benzo­yl)-4-nitro­phen­yl]-N-methyl­acetamide

The title compound, C(16)H(12)ClFN(2)O(4), crystallizes with two mol­ecules in the asymmetric unit in which the dihedral angles between the mean planes of the two benzene rings are 65.1 (7) and 65.6 (6)°. In each mol­ecule, the nitro group displays rotational disorder over two orientations in a 0.50...

Descripción completa

Detalles Bibliográficos
Autores principales: Siddaraju, B. P., Jasinski, Jerry P., Golen, James A., Yathirajan, H. S., Raju, C. R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200782/
https://www.ncbi.nlm.nih.gov/pubmed/22064922
http://dx.doi.org/10.1107/S1600536811034969
_version_ 1782214748350185472
author Siddaraju, B. P.
Jasinski, Jerry P.
Golen, James A.
Yathirajan, H. S.
Raju, C. R.
author_facet Siddaraju, B. P.
Jasinski, Jerry P.
Golen, James A.
Yathirajan, H. S.
Raju, C. R.
author_sort Siddaraju, B. P.
collection PubMed
description The title compound, C(16)H(12)ClFN(2)O(4), crystallizes with two mol­ecules in the asymmetric unit in which the dihedral angles between the mean planes of the two benzene rings are 65.1 (7) and 65.6 (6)°. In each mol­ecule, the nitro group displays rotational disorder over two orientations in a 0.503 (11):0.497 (11) ratio and the Cl atom is disordered in a 0.432 (5):0.568 (5) ratio. In one mol­ecule, the F atoms is statistically disordered over two positions. The crystal packing features weak inter­molecular C—H⋯O and C—H⋯Cl inter­actions, which form a layered network.
format Online
Article
Text
id pubmed-3200782
institution National Center for Biotechnology Information
language English
publishDate 2011
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-32007822011-11-06 2-Chloro-N-[2-(2-fluoro­benzo­yl)-4-nitro­phen­yl]-N-methyl­acetamide Siddaraju, B. P. Jasinski, Jerry P. Golen, James A. Yathirajan, H. S. Raju, C. R. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(16)H(12)ClFN(2)O(4), crystallizes with two mol­ecules in the asymmetric unit in which the dihedral angles between the mean planes of the two benzene rings are 65.1 (7) and 65.6 (6)°. In each mol­ecule, the nitro group displays rotational disorder over two orientations in a 0.503 (11):0.497 (11) ratio and the Cl atom is disordered in a 0.432 (5):0.568 (5) ratio. In one mol­ecule, the F atoms is statistically disordered over two positions. The crystal packing features weak inter­molecular C—H⋯O and C—H⋯Cl inter­actions, which form a layered network. International Union of Crystallography 2011-08-31 /pmc/articles/PMC3200782/ /pubmed/22064922 http://dx.doi.org/10.1107/S1600536811034969 Text en © Siddaraju et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Siddaraju, B. P.
Jasinski, Jerry P.
Golen, James A.
Yathirajan, H. S.
Raju, C. R.
2-Chloro-N-[2-(2-fluoro­benzo­yl)-4-nitro­phen­yl]-N-methyl­acetamide
title 2-Chloro-N-[2-(2-fluoro­benzo­yl)-4-nitro­phen­yl]-N-methyl­acetamide
title_full 2-Chloro-N-[2-(2-fluoro­benzo­yl)-4-nitro­phen­yl]-N-methyl­acetamide
title_fullStr 2-Chloro-N-[2-(2-fluoro­benzo­yl)-4-nitro­phen­yl]-N-methyl­acetamide
title_full_unstemmed 2-Chloro-N-[2-(2-fluoro­benzo­yl)-4-nitro­phen­yl]-N-methyl­acetamide
title_short 2-Chloro-N-[2-(2-fluoro­benzo­yl)-4-nitro­phen­yl]-N-methyl­acetamide
title_sort 2-chloro-n-[2-(2-fluoro­benzo­yl)-4-nitro­phen­yl]-n-methyl­acetamide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200782/
https://www.ncbi.nlm.nih.gov/pubmed/22064922
http://dx.doi.org/10.1107/S1600536811034969
work_keys_str_mv AT siddarajubp 2chloron22fluorobenzoyl4nitrophenylnmethylacetamide
AT jasinskijerryp 2chloron22fluorobenzoyl4nitrophenylnmethylacetamide
AT golenjamesa 2chloron22fluorobenzoyl4nitrophenylnmethylacetamide
AT yathirajanhs 2chloron22fluorobenzoyl4nitrophenylnmethylacetamide
AT rajucr 2chloron22fluorobenzoyl4nitrophenylnmethylacetamide

Ejemplares similares