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Bis[3,5-difluoro-2-(4-methylpyridin-2-yl)phenyl-κ(2) C (1),N](picolinato-κ(2) N,O)iridium(III) chloroform monosolvate
In the title complex, [Ir(C(12)H(8)F(2)N)(2)(C(6)H(4)NO(2))]·CHCl(3), two similar molecules of each component comprise the asymmetric unit. The independent complex molecules are linked by intermolecular π–π interactions [centroid–centroid distance = 3.830 (4) Å]. The Ir(III) ion adopts a distort...
| Autores principales: | , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2011
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200786/ https://www.ncbi.nlm.nih.gov/pubmed/22065292 http://dx.doi.org/10.1107/S1600536811030856 |
| _version_ | 1782214749240426496 |
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| author | Kim, Young-Inn Seo, Hoe-Joo Yun, Seong-Jae Song, Young-Kwang Kim, In-Chan Kang, Sung Kwon |
| author_facet | Kim, Young-Inn Seo, Hoe-Joo Yun, Seong-Jae Song, Young-Kwang Kim, In-Chan Kang, Sung Kwon |
| author_sort | Kim, Young-Inn |
| collection | PubMed |
| description | In the title complex, [Ir(C(12)H(8)F(2)N)(2)(C(6)H(4)NO(2))]·CHCl(3), two similar molecules of each component comprise the asymmetric unit. The independent complex molecules are linked by intermolecular π–π interactions [centroid–centroid distance = 3.830 (4) Å]. The Ir(III) ion adopts a distorted octahedral geometry, being coordinated by three N atoms, two C atoms, and one O atom of three bidentate ligands, with the N atoms arranged meridionally. |
| format | Online Article Text |
| id | pubmed-3200786 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-32007862011-11-06 Bis[3,5-difluoro-2-(4-methylpyridin-2-yl)phenyl-κ(2) C (1),N](picolinato-κ(2) N,O)iridium(III) chloroform monosolvate Kim, Young-Inn Seo, Hoe-Joo Yun, Seong-Jae Song, Young-Kwang Kim, In-Chan Kang, Sung Kwon Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Ir(C(12)H(8)F(2)N)(2)(C(6)H(4)NO(2))]·CHCl(3), two similar molecules of each component comprise the asymmetric unit. The independent complex molecules are linked by intermolecular π–π interactions [centroid–centroid distance = 3.830 (4) Å]. The Ir(III) ion adopts a distorted octahedral geometry, being coordinated by three N atoms, two C atoms, and one O atom of three bidentate ligands, with the N atoms arranged meridionally. International Union of Crystallography 2011-08-06 /pmc/articles/PMC3200786/ /pubmed/22065292 http://dx.doi.org/10.1107/S1600536811030856 Text en © Kim et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Kim, Young-Inn Seo, Hoe-Joo Yun, Seong-Jae Song, Young-Kwang Kim, In-Chan Kang, Sung Kwon Bis[3,5-difluoro-2-(4-methylpyridin-2-yl)phenyl-κ(2) C (1),N](picolinato-κ(2) N,O)iridium(III) chloroform monosolvate |
| title | Bis[3,5-difluoro-2-(4-methylpyridin-2-yl)phenyl-κ(2)
C
(1),N](picolinato-κ(2)
N,O)iridium(III) chloroform monosolvate |
| title_full | Bis[3,5-difluoro-2-(4-methylpyridin-2-yl)phenyl-κ(2)
C
(1),N](picolinato-κ(2)
N,O)iridium(III) chloroform monosolvate |
| title_fullStr | Bis[3,5-difluoro-2-(4-methylpyridin-2-yl)phenyl-κ(2)
C
(1),N](picolinato-κ(2)
N,O)iridium(III) chloroform monosolvate |
| title_full_unstemmed | Bis[3,5-difluoro-2-(4-methylpyridin-2-yl)phenyl-κ(2)
C
(1),N](picolinato-κ(2)
N,O)iridium(III) chloroform monosolvate |
| title_short | Bis[3,5-difluoro-2-(4-methylpyridin-2-yl)phenyl-κ(2)
C
(1),N](picolinato-κ(2)
N,O)iridium(III) chloroform monosolvate |
| title_sort | bis[3,5-difluoro-2-(4-methylpyridin-2-yl)phenyl-κ(2)
c
(1),n](picolinato-κ(2)
n,o)iridium(iii) chloroform monosolvate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200786/ https://www.ncbi.nlm.nih.gov/pubmed/22065292 http://dx.doi.org/10.1107/S1600536811030856 |
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