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(2-{[2-(1H-Benzimidazol-2-yl-κN (3))phenyl]iminomethyl-κN}-5-methylphenolato-κO)chloridozinc(II)
In the title mononuclear complex, [Zn(C(21)H(16)N(3)O)Cl], the Zn(II) ion is coordinated in a distorted tetrahedral geometry by two benzimidazole N atoms and one phenolate O atom from the tridentate Schiff base ligand and a chloride ligand. The benzimidazole ring system forms dihedral angles of 26....
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200787/ https://www.ncbi.nlm.nih.gov/pubmed/22065469 http://dx.doi.org/10.1107/S1600536811030170 |
Sumario: | In the title mononuclear complex, [Zn(C(21)H(16)N(3)O)Cl], the Zn(II) ion is coordinated in a distorted tetrahedral geometry by two benzimidazole N atoms and one phenolate O atom from the tridentate Schiff base ligand and a chloride ligand. The benzimidazole ring system forms dihedral angles of 26.68 (9) and 56.16 (9)° with the adjacent benzene ring and the methylphenolate group benzene ring, respectively. In the crystal, molecules are linked by N—H⋯Cl hydrogen bonds into chains along [100]. Furthermore, weak C—H⋯O and C—H⋯π interactions, in addition to π–π interactions with centroid–centroid distances in the range 3.5826 (13)–3.9681 (13) Å, are also observed. |
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