Cargando…

1-(4-Chloro­benzo­yl)-3-(3-methyl­pyridin-2-yl)thio­urea

The mol­ecule of the title compound, C(14)H(12)ClN(3)OS, consists of three approximately planar fragments: the central thio­urea group, the chloro­phenyl group and the picolyl (3-methyl­pyridin-2-yl) group with a maximum of 0.035 (2)° for an N atom from the mean square plane of the central thiourea...

Descripción completa

Detalles Bibliográficos
Autores principales: Yusof, M.Sukeri M., Mushtari, Nurwahyuni A., Kadir, Maisara A., Yamin, Bohari M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200797/
https://www.ncbi.nlm.nih.gov/pubmed/22058973
http://dx.doi.org/10.1107/S1600536811032375
Descripción
Sumario:The mol­ecule of the title compound, C(14)H(12)ClN(3)OS, consists of three approximately planar fragments: the central thio­urea group, the chloro­phenyl group and the picolyl (3-methyl­pyridin-2-yl) group with a maximum of 0.035 (2)° for an N atom from the mean square plane of the central thiourea group. The central fragment forms dihedral angles of 33.30 (8) and 76.78 (8)° with the chloro­phenyl and picolyl groups, respectively. With respect to the thio­urea C—N bonds, the 4-chloro­benzoyl group is positioned trans to the thiono S atoms, whereas the picolyl group lies in a cis position to it. The mol­ecular conformation is stabilized by an intra­molecular N—H⋯O hydrogen bond. In the crystal, mol­ecules are linked by inter­molecular C—H⋯N hydrogen bonds, forming chains along the a axis.