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1-(4-Chloro­benzo­yl)-3-(3-methyl­pyridin-2-yl)thio­urea

The mol­ecule of the title compound, C(14)H(12)ClN(3)OS, consists of three approximately planar fragments: the central thio­urea group, the chloro­phenyl group and the picolyl (3-methyl­pyridin-2-yl) group with a maximum of 0.035 (2)° for an N atom from the mean square plane of the central thiourea...

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Autores principales: Yusof, M.Sukeri M., Mushtari, Nurwahyuni A., Kadir, Maisara A., Yamin, Bohari M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200797/
https://www.ncbi.nlm.nih.gov/pubmed/22058973
http://dx.doi.org/10.1107/S1600536811032375
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author Yusof, M.Sukeri M.
Mushtari, Nurwahyuni A.
Kadir, Maisara A.
Yamin, Bohari M.
author_facet Yusof, M.Sukeri M.
Mushtari, Nurwahyuni A.
Kadir, Maisara A.
Yamin, Bohari M.
author_sort Yusof, M.Sukeri M.
collection PubMed
description The mol­ecule of the title compound, C(14)H(12)ClN(3)OS, consists of three approximately planar fragments: the central thio­urea group, the chloro­phenyl group and the picolyl (3-methyl­pyridin-2-yl) group with a maximum of 0.035 (2)° for an N atom from the mean square plane of the central thiourea group. The central fragment forms dihedral angles of 33.30 (8) and 76.78 (8)° with the chloro­phenyl and picolyl groups, respectively. With respect to the thio­urea C—N bonds, the 4-chloro­benzoyl group is positioned trans to the thiono S atoms, whereas the picolyl group lies in a cis position to it. The mol­ecular conformation is stabilized by an intra­molecular N—H⋯O hydrogen bond. In the crystal, mol­ecules are linked by inter­molecular C—H⋯N hydrogen bonds, forming chains along the a axis.
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spelling pubmed-32007972011-11-06 1-(4-Chloro­benzo­yl)-3-(3-methyl­pyridin-2-yl)thio­urea Yusof, M.Sukeri M. Mushtari, Nurwahyuni A. Kadir, Maisara A. Yamin, Bohari M. Acta Crystallogr Sect E Struct Rep Online Organic Papers The mol­ecule of the title compound, C(14)H(12)ClN(3)OS, consists of three approximately planar fragments: the central thio­urea group, the chloro­phenyl group and the picolyl (3-methyl­pyridin-2-yl) group with a maximum of 0.035 (2)° for an N atom from the mean square plane of the central thiourea group. The central fragment forms dihedral angles of 33.30 (8) and 76.78 (8)° with the chloro­phenyl and picolyl groups, respectively. With respect to the thio­urea C—N bonds, the 4-chloro­benzoyl group is positioned trans to the thiono S atoms, whereas the picolyl group lies in a cis position to it. The mol­ecular conformation is stabilized by an intra­molecular N—H⋯O hydrogen bond. In the crystal, mol­ecules are linked by inter­molecular C—H⋯N hydrogen bonds, forming chains along the a axis. International Union of Crystallography 2011-08-17 /pmc/articles/PMC3200797/ /pubmed/22058973 http://dx.doi.org/10.1107/S1600536811032375 Text en © Yusof et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Yusof, M.Sukeri M.
Mushtari, Nurwahyuni A.
Kadir, Maisara A.
Yamin, Bohari M.
1-(4-Chloro­benzo­yl)-3-(3-methyl­pyridin-2-yl)thio­urea
title 1-(4-Chloro­benzo­yl)-3-(3-methyl­pyridin-2-yl)thio­urea
title_full 1-(4-Chloro­benzo­yl)-3-(3-methyl­pyridin-2-yl)thio­urea
title_fullStr 1-(4-Chloro­benzo­yl)-3-(3-methyl­pyridin-2-yl)thio­urea
title_full_unstemmed 1-(4-Chloro­benzo­yl)-3-(3-methyl­pyridin-2-yl)thio­urea
title_short 1-(4-Chloro­benzo­yl)-3-(3-methyl­pyridin-2-yl)thio­urea
title_sort 1-(4-chloro­benzo­yl)-3-(3-methyl­pyridin-2-yl)thio­urea
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200797/
https://www.ncbi.nlm.nih.gov/pubmed/22058973
http://dx.doi.org/10.1107/S1600536811032375
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AT mushtarinurwahyunia 14chlorobenzoyl33methylpyridin2ylthiourea
AT kadirmaisaraa 14chlorobenzoyl33methylpyridin2ylthiourea
AT yaminboharim 14chlorobenzoyl33methylpyridin2ylthiourea