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4-(1,3-Benzodioxol-5-yl)-2-oxo-1,2,5,6-tetrahydrobenzo[h]quinoline-3-carbonitrile
In the molecule of the title compound, C(21)H(14)N(2)O(3), the tetrahydrobenzo[h]quinoline fused-ring system is buckled owing to the ethylene –CH(2)CH(2)– fragment, the benzene ring and the pyridine ring being twisted by 24.3 (1)°. The ring of the benzodioxol system is bent away from the pyridin...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2011
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200803/ https://www.ncbi.nlm.nih.gov/pubmed/22064284 http://dx.doi.org/10.1107/S1600536811033903 |
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| author | Asiri, Abdullah M. Faidallah, Hassan M. Al-Youbi, Abdulrahman O. Alamry, Khalid A. Ng, Seik Weng |
| author_facet | Asiri, Abdullah M. Faidallah, Hassan M. Al-Youbi, Abdulrahman O. Alamry, Khalid A. Ng, Seik Weng |
| author_sort | Asiri, Abdullah M. |
| collection | PubMed |
| description | In the molecule of the title compound, C(21)H(14)N(2)O(3), the tetrahydrobenzo[h]quinoline fused-ring system is buckled owing to the ethylene –CH(2)CH(2)– fragment, the benzene ring and the pyridine ring being twisted by 24.3 (1)°. The ring of the benzodioxol system is bent away from the pyridine ring by 61.4 (1)° in order to avoid crowding the cyanide substituent. Two molecules are linked by a pair of N—H⋯O hydrogen bonds to form a centrosymmetric dimer. |
| format | Online Article Text |
| id | pubmed-3200803 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-32008032011-11-06 4-(1,3-Benzodioxol-5-yl)-2-oxo-1,2,5,6-tetrahydrobenzo[h]quinoline-3-carbonitrile Asiri, Abdullah M. Faidallah, Hassan M. Al-Youbi, Abdulrahman O. Alamry, Khalid A. Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Organic Papers In the molecule of the title compound, C(21)H(14)N(2)O(3), the tetrahydrobenzo[h]quinoline fused-ring system is buckled owing to the ethylene –CH(2)CH(2)– fragment, the benzene ring and the pyridine ring being twisted by 24.3 (1)°. The ring of the benzodioxol system is bent away from the pyridine ring by 61.4 (1)° in order to avoid crowding the cyanide substituent. Two molecules are linked by a pair of N—H⋯O hydrogen bonds to form a centrosymmetric dimer. International Union of Crystallography 2011-08-27 /pmc/articles/PMC3200803/ /pubmed/22064284 http://dx.doi.org/10.1107/S1600536811033903 Text en © Asiri et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Organic Papers Asiri, Abdullah M. Faidallah, Hassan M. Al-Youbi, Abdulrahman O. Alamry, Khalid A. Ng, Seik Weng 4-(1,3-Benzodioxol-5-yl)-2-oxo-1,2,5,6-tetrahydrobenzo[h]quinoline-3-carbonitrile |
| title | 4-(1,3-Benzodioxol-5-yl)-2-oxo-1,2,5,6-tetrahydrobenzo[h]quinoline-3-carbonitrile |
| title_full | 4-(1,3-Benzodioxol-5-yl)-2-oxo-1,2,5,6-tetrahydrobenzo[h]quinoline-3-carbonitrile |
| title_fullStr | 4-(1,3-Benzodioxol-5-yl)-2-oxo-1,2,5,6-tetrahydrobenzo[h]quinoline-3-carbonitrile |
| title_full_unstemmed | 4-(1,3-Benzodioxol-5-yl)-2-oxo-1,2,5,6-tetrahydrobenzo[h]quinoline-3-carbonitrile |
| title_short | 4-(1,3-Benzodioxol-5-yl)-2-oxo-1,2,5,6-tetrahydrobenzo[h]quinoline-3-carbonitrile |
| title_sort | 4-(1,3-benzodioxol-5-yl)-2-oxo-1,2,5,6-tetrahydrobenzo[h]quinoline-3-carbonitrile |
| topic | Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200803/ https://www.ncbi.nlm.nih.gov/pubmed/22064284 http://dx.doi.org/10.1107/S1600536811033903 |
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