6,7,6′,7′-Tetra­phenyl-2,2′-bi[1,3-dithia-5,8-diaza­cyclo­penta­[b]naphthalenyl­idene] chloro­form disolvate

The title compound, C(42)H(24)N(4)S(4)·2CHCl(3), a symmetrical tetra­thia­fulvalene (TTF) derivative, was prepared by a tri­ethyl­phos­phite-mediated self-coupling reaction of 6,7-diphenyl-1,3-dithia-5,8-diaza­cyclo­penta­[b]napthalen-2-one. The asymmetric unit contains two TTF mol­ecules and four c...

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Autores principales: Bolligarla, Ramababu, Durgaprasad, Gummadi, Das, Samar K.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200811/
https://www.ncbi.nlm.nih.gov/pubmed/22064676
http://dx.doi.org/10.1107/S1600536811029540
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author Bolligarla, Ramababu
Durgaprasad, Gummadi
Das, Samar K.
author_facet Bolligarla, Ramababu
Durgaprasad, Gummadi
Das, Samar K.
author_sort Bolligarla, Ramababu
collection PubMed
description The title compound, C(42)H(24)N(4)S(4)·2CHCl(3), a symmetrical tetra­thia­fulvalene (TTF) derivative, was prepared by a tri­ethyl­phos­phite-mediated self-coupling reaction of 6,7-diphenyl-1,3-dithia-5,8-diaza­cyclo­penta­[b]napthalen-2-one. The asymmetric unit contains two TTF mol­ecules and four chloro­form solvent mol­ecules. Cl⋯Cl inter­actions [contact distances = 3.263 (1)–3.395 (2) Å] are present between the solvent mol­ecules, resulting in a tape along the bc plane. The crystal packing features weak C—H⋯Cl and C—H⋯N hydrogen bonds, resulting in the formation of a two-dimensional supramolecular network.
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spelling pubmed-32008112011-11-06 6,7,6′,7′-Tetra­phenyl-2,2′-bi[1,3-dithia-5,8-diaza­cyclo­penta­[b]naphthalenyl­idene] chloro­form disolvate Bolligarla, Ramababu Durgaprasad, Gummadi Das, Samar K. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(42)H(24)N(4)S(4)·2CHCl(3), a symmetrical tetra­thia­fulvalene (TTF) derivative, was prepared by a tri­ethyl­phos­phite-mediated self-coupling reaction of 6,7-diphenyl-1,3-dithia-5,8-diaza­cyclo­penta­[b]napthalen-2-one. The asymmetric unit contains two TTF mol­ecules and four chloro­form solvent mol­ecules. Cl⋯Cl inter­actions [contact distances = 3.263 (1)–3.395 (2) Å] are present between the solvent mol­ecules, resulting in a tape along the bc plane. The crystal packing features weak C—H⋯Cl and C—H⋯N hydrogen bonds, resulting in the formation of a two-dimensional supramolecular network. International Union of Crystallography 2011-08-02 /pmc/articles/PMC3200811/ /pubmed/22064676 http://dx.doi.org/10.1107/S1600536811029540 Text en © Bolligarla et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Bolligarla, Ramababu
Durgaprasad, Gummadi
Das, Samar K.
6,7,6′,7′-Tetra­phenyl-2,2′-bi[1,3-dithia-5,8-diaza­cyclo­penta­[b]naphthalenyl­idene] chloro­form disolvate
title 6,7,6′,7′-Tetra­phenyl-2,2′-bi[1,3-dithia-5,8-diaza­cyclo­penta­[b]naphthalenyl­idene] chloro­form disolvate
title_full 6,7,6′,7′-Tetra­phenyl-2,2′-bi[1,3-dithia-5,8-diaza­cyclo­penta­[b]naphthalenyl­idene] chloro­form disolvate
title_fullStr 6,7,6′,7′-Tetra­phenyl-2,2′-bi[1,3-dithia-5,8-diaza­cyclo­penta­[b]naphthalenyl­idene] chloro­form disolvate
title_full_unstemmed 6,7,6′,7′-Tetra­phenyl-2,2′-bi[1,3-dithia-5,8-diaza­cyclo­penta­[b]naphthalenyl­idene] chloro­form disolvate
title_short 6,7,6′,7′-Tetra­phenyl-2,2′-bi[1,3-dithia-5,8-diaza­cyclo­penta­[b]naphthalenyl­idene] chloro­form disolvate
title_sort 6,7,6′,7′-tetra­phenyl-2,2′-bi[1,3-dithia-5,8-diaza­cyclo­penta­[b]naphthalenyl­idene] chloro­form disolvate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200811/
https://www.ncbi.nlm.nih.gov/pubmed/22064676
http://dx.doi.org/10.1107/S1600536811029540
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AT dassamark 6767tetraphenyl22bi13dithia58diazacyclopentabnaphthalenylidenechloroformdisolvate

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