Bis(1-benzyl-3-methyl­imidazolium-κC (2))mercury(II) bis­(hexa­fluoridophosphate)

The asymmetric unit of the title complex, [Hg(C(11)H(12)N(2))(2)](PF(6))(2), consists of one bis­(1-benzyl-3-methyl­imidazolium)mercury(II) cation, one half of the cation and an additional Hg(II) atom, which lies on an inversion centre, and three hexa­fluorido­phosphate anions. The Hg(II) atoms exis...

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Detalles Bibliográficos
Autores principales: Haque, Rosenani A., Salman, Abbas Washeel, Hemamalini, Madhukar, Fun, Hoong-Kun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200814/
https://www.ncbi.nlm.nih.gov/pubmed/22064754
http://dx.doi.org/10.1107/S1600536811032235
Descripción
Sumario:The asymmetric unit of the title complex, [Hg(C(11)H(12)N(2))(2)](PF(6))(2), consists of one bis­(1-benzyl-3-methyl­imidazolium)mercury(II) cation, one half of the cation and an additional Hg(II) atom, which lies on an inversion centre, and three hexa­fluorido­phosphate anions. The Hg(II) atoms exist in a linear coordination geometry [C—Hg—C = 178.9 (2) and 180°] formed by two carbene C atoms from the imidazole rings. In the crystal, the cations and anions are connected via C—H⋯F hydrogen bonds, forming a three-dimensional network.

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