Bis(1-benzyl-3-methyl­imidazolium-κC (2))mercury(II) bis­(hexa­fluoridophosphate)

The asymmetric unit of the title complex, [Hg(C(11)H(12)N(2))(2)](PF(6))(2), consists of one bis­(1-benzyl-3-methyl­imidazolium)mercury(II) cation, one half of the cation and an additional Hg(II) atom, which lies on an inversion centre, and three hexa­fluorido­phosphate anions. The Hg(II) atoms exis...

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Autores principales: Haque, Rosenani A., Salman, Abbas Washeel, Hemamalini, Madhukar, Fun, Hoong-Kun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200814/
https://www.ncbi.nlm.nih.gov/pubmed/22064754
http://dx.doi.org/10.1107/S1600536811032235
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author Haque, Rosenani A.
Salman, Abbas Washeel
Hemamalini, Madhukar
Fun, Hoong-Kun
author_facet Haque, Rosenani A.
Salman, Abbas Washeel
Hemamalini, Madhukar
Fun, Hoong-Kun
author_sort Haque, Rosenani A.
collection PubMed
description The asymmetric unit of the title complex, [Hg(C(11)H(12)N(2))(2)](PF(6))(2), consists of one bis­(1-benzyl-3-methyl­imidazolium)mercury(II) cation, one half of the cation and an additional Hg(II) atom, which lies on an inversion centre, and three hexa­fluorido­phosphate anions. The Hg(II) atoms exist in a linear coordination geometry [C—Hg—C = 178.9 (2) and 180°] formed by two carbene C atoms from the imidazole rings. In the crystal, the cations and anions are connected via C—H⋯F hydrogen bonds, forming a three-dimensional network.
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spelling pubmed-32008142011-11-06 Bis(1-benzyl-3-methyl­imidazolium-κC (2))mercury(II) bis­(hexa­fluoridophosphate) Haque, Rosenani A. Salman, Abbas Washeel Hemamalini, Madhukar Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title complex, [Hg(C(11)H(12)N(2))(2)](PF(6))(2), consists of one bis­(1-benzyl-3-methyl­imidazolium)mercury(II) cation, one half of the cation and an additional Hg(II) atom, which lies on an inversion centre, and three hexa­fluorido­phosphate anions. The Hg(II) atoms exist in a linear coordination geometry [C—Hg—C = 178.9 (2) and 180°] formed by two carbene C atoms from the imidazole rings. In the crystal, the cations and anions are connected via C—H⋯F hydrogen bonds, forming a three-dimensional network. International Union of Crystallography 2011-08-17 /pmc/articles/PMC3200814/ /pubmed/22064754 http://dx.doi.org/10.1107/S1600536811032235 Text en © Haque et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Haque, Rosenani A.
Salman, Abbas Washeel
Hemamalini, Madhukar
Fun, Hoong-Kun
Bis(1-benzyl-3-methyl­imidazolium-κC (2))mercury(II) bis­(hexa­fluoridophosphate)
title Bis(1-benzyl-3-methyl­imidazolium-κC (2))mercury(II) bis­(hexa­fluoridophosphate)
title_full Bis(1-benzyl-3-methyl­imidazolium-κC (2))mercury(II) bis­(hexa­fluoridophosphate)
title_fullStr Bis(1-benzyl-3-methyl­imidazolium-κC (2))mercury(II) bis­(hexa­fluoridophosphate)
title_full_unstemmed Bis(1-benzyl-3-methyl­imidazolium-κC (2))mercury(II) bis­(hexa­fluoridophosphate)
title_short Bis(1-benzyl-3-methyl­imidazolium-κC (2))mercury(II) bis­(hexa­fluoridophosphate)
title_sort bis(1-benzyl-3-methyl­imidazolium-κc (2))mercury(ii) bis­(hexa­fluoridophosphate)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200814/
https://www.ncbi.nlm.nih.gov/pubmed/22064754
http://dx.doi.org/10.1107/S1600536811032235
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