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(E)-N′-[1-(Thio­phen-2-yl)ethyl­idene]benzohydrazide

The title compound, C(13)H(12)N(2)OS, was obtained from the condensation reaction of 2-acetyl­thio­phene and benzohydrazide. In the mol­ecule, the formohydrazide fragment is approximately planar (r.m.s deviation = 0.0146 Å) and the mean plane is oriented at dihedral angles of 24.47 (11) and 28.86 (1...

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Detalles Bibliográficos
Autores principales: Shan, Shang, Huang, Yan-Lan, Guo, Han-Qi, Li, Deng-Feng, Sun, Jian
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200815/
https://www.ncbi.nlm.nih.gov/pubmed/22059048
http://dx.doi.org/10.1107/S1600536811033101
Descripción
Sumario:The title compound, C(13)H(12)N(2)OS, was obtained from the condensation reaction of 2-acetyl­thio­phene and benzohydrazide. In the mol­ecule, the formohydrazide fragment is approximately planar (r.m.s deviation = 0.0146 Å) and the mean plane is oriented at dihedral angles of 24.47 (11) and 28.86 (13)°, respectively, to the phenyl and thio­phene rings. The thio­phene and phenyl rings make a dihedral angle of 53.21 (8)°. The benzamide fragment and thio­phene ring are located on the opposite sides of the C=N bond, showing an E conformation. Classical inter­molecular N—H⋯O hydrogen bonds and weak C—H⋯O inter­actions are present in the crystal structure: three such bonds occur to the same O-atom acceptor.