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(E)-N′-[1-(Thiophen-2-yl)ethylidene]benzohydrazide
The title compound, C(13)H(12)N(2)OS, was obtained from the condensation reaction of 2-acetylthiophene and benzohydrazide. In the molecule, the formohydrazide fragment is approximately planar (r.m.s deviation = 0.0146 Å) and the mean plane is oriented at dihedral angles of 24.47 (11) and 28.86 (1...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200815/ https://www.ncbi.nlm.nih.gov/pubmed/22059048 http://dx.doi.org/10.1107/S1600536811033101 |
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author | Shan, Shang Huang, Yan-Lan Guo, Han-Qi Li, Deng-Feng Sun, Jian |
author_facet | Shan, Shang Huang, Yan-Lan Guo, Han-Qi Li, Deng-Feng Sun, Jian |
author_sort | Shan, Shang |
collection | PubMed |
description | The title compound, C(13)H(12)N(2)OS, was obtained from the condensation reaction of 2-acetylthiophene and benzohydrazide. In the molecule, the formohydrazide fragment is approximately planar (r.m.s deviation = 0.0146 Å) and the mean plane is oriented at dihedral angles of 24.47 (11) and 28.86 (13)°, respectively, to the phenyl and thiophene rings. The thiophene and phenyl rings make a dihedral angle of 53.21 (8)°. The benzamide fragment and thiophene ring are located on the opposite sides of the C=N bond, showing an E conformation. Classical intermolecular N—H⋯O hydrogen bonds and weak C—H⋯O interactions are present in the crystal structure: three such bonds occur to the same O-atom acceptor. |
format | Online Article Text |
id | pubmed-3200815 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32008152011-11-06 (E)-N′-[1-(Thiophen-2-yl)ethylidene]benzohydrazide Shan, Shang Huang, Yan-Lan Guo, Han-Qi Li, Deng-Feng Sun, Jian Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(13)H(12)N(2)OS, was obtained from the condensation reaction of 2-acetylthiophene and benzohydrazide. In the molecule, the formohydrazide fragment is approximately planar (r.m.s deviation = 0.0146 Å) and the mean plane is oriented at dihedral angles of 24.47 (11) and 28.86 (13)°, respectively, to the phenyl and thiophene rings. The thiophene and phenyl rings make a dihedral angle of 53.21 (8)°. The benzamide fragment and thiophene ring are located on the opposite sides of the C=N bond, showing an E conformation. Classical intermolecular N—H⋯O hydrogen bonds and weak C—H⋯O interactions are present in the crystal structure: three such bonds occur to the same O-atom acceptor. International Union of Crystallography 2011-08-27 /pmc/articles/PMC3200815/ /pubmed/22059048 http://dx.doi.org/10.1107/S1600536811033101 Text en © Shan et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Shan, Shang Huang, Yan-Lan Guo, Han-Qi Li, Deng-Feng Sun, Jian (E)-N′-[1-(Thiophen-2-yl)ethylidene]benzohydrazide |
title | (E)-N′-[1-(Thiophen-2-yl)ethylidene]benzohydrazide |
title_full | (E)-N′-[1-(Thiophen-2-yl)ethylidene]benzohydrazide |
title_fullStr | (E)-N′-[1-(Thiophen-2-yl)ethylidene]benzohydrazide |
title_full_unstemmed | (E)-N′-[1-(Thiophen-2-yl)ethylidene]benzohydrazide |
title_short | (E)-N′-[1-(Thiophen-2-yl)ethylidene]benzohydrazide |
title_sort | (e)-n′-[1-(thiophen-2-yl)ethylidene]benzohydrazide |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200815/ https://www.ncbi.nlm.nih.gov/pubmed/22059048 http://dx.doi.org/10.1107/S1600536811033101 |
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