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(E)-N′-[1-(Thio­phen-2-yl)ethyl­idene]benzohydrazide

The title compound, C(13)H(12)N(2)OS, was obtained from the condensation reaction of 2-acetyl­thio­phene and benzohydrazide. In the mol­ecule, the formohydrazide fragment is approximately planar (r.m.s deviation = 0.0146 Å) and the mean plane is oriented at dihedral angles of 24.47 (11) and 28.86 (1...

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Autores principales: Shan, Shang, Huang, Yan-Lan, Guo, Han-Qi, Li, Deng-Feng, Sun, Jian
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200815/
https://www.ncbi.nlm.nih.gov/pubmed/22059048
http://dx.doi.org/10.1107/S1600536811033101
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author Shan, Shang
Huang, Yan-Lan
Guo, Han-Qi
Li, Deng-Feng
Sun, Jian
author_facet Shan, Shang
Huang, Yan-Lan
Guo, Han-Qi
Li, Deng-Feng
Sun, Jian
author_sort Shan, Shang
collection PubMed
description The title compound, C(13)H(12)N(2)OS, was obtained from the condensation reaction of 2-acetyl­thio­phene and benzohydrazide. In the mol­ecule, the formohydrazide fragment is approximately planar (r.m.s deviation = 0.0146 Å) and the mean plane is oriented at dihedral angles of 24.47 (11) and 28.86 (13)°, respectively, to the phenyl and thio­phene rings. The thio­phene and phenyl rings make a dihedral angle of 53.21 (8)°. The benzamide fragment and thio­phene ring are located on the opposite sides of the C=N bond, showing an E conformation. Classical inter­molecular N—H⋯O hydrogen bonds and weak C—H⋯O inter­actions are present in the crystal structure: three such bonds occur to the same O-atom acceptor.
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spelling pubmed-32008152011-11-06 (E)-N′-[1-(Thio­phen-2-yl)ethyl­idene]benzohydrazide Shan, Shang Huang, Yan-Lan Guo, Han-Qi Li, Deng-Feng Sun, Jian Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(13)H(12)N(2)OS, was obtained from the condensation reaction of 2-acetyl­thio­phene and benzohydrazide. In the mol­ecule, the formohydrazide fragment is approximately planar (r.m.s deviation = 0.0146 Å) and the mean plane is oriented at dihedral angles of 24.47 (11) and 28.86 (13)°, respectively, to the phenyl and thio­phene rings. The thio­phene and phenyl rings make a dihedral angle of 53.21 (8)°. The benzamide fragment and thio­phene ring are located on the opposite sides of the C=N bond, showing an E conformation. Classical inter­molecular N—H⋯O hydrogen bonds and weak C—H⋯O inter­actions are present in the crystal structure: three such bonds occur to the same O-atom acceptor. International Union of Crystallography 2011-08-27 /pmc/articles/PMC3200815/ /pubmed/22059048 http://dx.doi.org/10.1107/S1600536811033101 Text en © Shan et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Shan, Shang
Huang, Yan-Lan
Guo, Han-Qi
Li, Deng-Feng
Sun, Jian
(E)-N′-[1-(Thio­phen-2-yl)ethyl­idene]benzohydrazide
title (E)-N′-[1-(Thio­phen-2-yl)ethyl­idene]benzohydrazide
title_full (E)-N′-[1-(Thio­phen-2-yl)ethyl­idene]benzohydrazide
title_fullStr (E)-N′-[1-(Thio­phen-2-yl)ethyl­idene]benzohydrazide
title_full_unstemmed (E)-N′-[1-(Thio­phen-2-yl)ethyl­idene]benzohydrazide
title_short (E)-N′-[1-(Thio­phen-2-yl)ethyl­idene]benzohydrazide
title_sort (e)-n′-[1-(thio­phen-2-yl)ethyl­idene]benzohydrazide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200815/
https://www.ncbi.nlm.nih.gov/pubmed/22059048
http://dx.doi.org/10.1107/S1600536811033101
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