Dichlorido[3-meth­oxy­methyl-4-phenyl-5-(2-pyrid­yl)-4H-1,2,4-triazole-κ(2) N (1),N (5)]copper(II)

In the title complex, [CuCl(2)(C(15)H(14)N(4)O)], the Cu(II) atom possesses a highly distorted square-planar geometry with N—Cu—N and Cl—Cu—Cl angles of 79.86 (8) and 98.65 (3)°, respectively, while the Cl—Cu—N angles fall into two distinct groups with values of 95.26 (6), 98.75 (6), 150.56 (6) and...

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Detalles Bibliográficos
Autores principales: Cao, Shouping, Wang, Zuoxiang, Jin, Xiaofei
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200827/
https://www.ncbi.nlm.nih.gov/pubmed/22058873
http://dx.doi.org/10.1107/S160053681103296X
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author Cao, Shouping
Wang, Zuoxiang
Jin, Xiaofei
author_facet Cao, Shouping
Wang, Zuoxiang
Jin, Xiaofei
author_sort Cao, Shouping
collection PubMed
description In the title complex, [CuCl(2)(C(15)H(14)N(4)O)], the Cu(II) atom possesses a highly distorted square-planar geometry with N—Cu—N and Cl—Cu—Cl angles of 79.86 (8) and 98.65 (3)°, respectively, while the Cl—Cu—N angles fall into two distinct groups with values of 95.26 (6), 98.75 (6), 150.56 (6) and 152.04 (6)°. The pyridyl ring is twisted by 9.4 (2)° with respect to the triazole ring, which is oriented at approximately right angles [84.66 (8)°] with respect to the phenyl ring.
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spelling pubmed-32008272011-11-06 Dichlorido[3-meth­oxy­methyl-4-phenyl-5-(2-pyrid­yl)-4H-1,2,4-triazole-κ(2) N (1),N (5)]copper(II) Cao, Shouping Wang, Zuoxiang Jin, Xiaofei Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [CuCl(2)(C(15)H(14)N(4)O)], the Cu(II) atom possesses a highly distorted square-planar geometry with N—Cu—N and Cl—Cu—Cl angles of 79.86 (8) and 98.65 (3)°, respectively, while the Cl—Cu—N angles fall into two distinct groups with values of 95.26 (6), 98.75 (6), 150.56 (6) and 152.04 (6)°. The pyridyl ring is twisted by 9.4 (2)° with respect to the triazole ring, which is oriented at approximately right angles [84.66 (8)°] with respect to the phenyl ring. International Union of Crystallography 2011-08-27 /pmc/articles/PMC3200827/ /pubmed/22058873 http://dx.doi.org/10.1107/S160053681103296X Text en © Cao et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Cao, Shouping
Wang, Zuoxiang
Jin, Xiaofei
Dichlorido[3-meth­oxy­methyl-4-phenyl-5-(2-pyrid­yl)-4H-1,2,4-triazole-κ(2) N (1),N (5)]copper(II)
title Dichlorido[3-meth­oxy­methyl-4-phenyl-5-(2-pyrid­yl)-4H-1,2,4-triazole-κ(2) N (1),N (5)]copper(II)
title_full Dichlorido[3-meth­oxy­methyl-4-phenyl-5-(2-pyrid­yl)-4H-1,2,4-triazole-κ(2) N (1),N (5)]copper(II)
title_fullStr Dichlorido[3-meth­oxy­methyl-4-phenyl-5-(2-pyrid­yl)-4H-1,2,4-triazole-κ(2) N (1),N (5)]copper(II)
title_full_unstemmed Dichlorido[3-meth­oxy­methyl-4-phenyl-5-(2-pyrid­yl)-4H-1,2,4-triazole-κ(2) N (1),N (5)]copper(II)
title_short Dichlorido[3-meth­oxy­methyl-4-phenyl-5-(2-pyrid­yl)-4H-1,2,4-triazole-κ(2) N (1),N (5)]copper(II)
title_sort dichlorido[3-meth­oxy­methyl-4-phenyl-5-(2-pyrid­yl)-4h-1,2,4-triazole-κ(2) n (1),n (5)]copper(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200827/
https://www.ncbi.nlm.nih.gov/pubmed/22058873
http://dx.doi.org/10.1107/S160053681103296X
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AT jinxiaofei dichlorido3methoxymethyl4phenyl52pyridyl4h124triazolek2n1n5copperii

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