2,2′-Bis(meth­oxy­meth­oxy)-3-methyl-1,1′-binaphth­yl

The title compound, C(25)H(24)O(4), a meth­oxy­methyl (MOM) bis-protected BINOL derivative containing a methyl substituent in position 3, is a key inter­mediate for the synthesis of a great variety of chiral auxiliaries. The planes of the naphthyl aromatic rings are at an angle of 70.74 (3)°. There...

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Detalles Bibliográficos
Autores principales: Carrilho, Rui M. B., Abreu, Artur R., Pereira, Mariette M., Rodrigues, V. H.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200832/
https://www.ncbi.nlm.nih.gov/pubmed/22058976
http://dx.doi.org/10.1107/S1600536811031722
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author Carrilho, Rui M. B.
Abreu, Artur R.
Pereira, Mariette M.
Rodrigues, V. H.
author_facet Carrilho, Rui M. B.
Abreu, Artur R.
Pereira, Mariette M.
Rodrigues, V. H.
author_sort Carrilho, Rui M. B.
collection PubMed
description The title compound, C(25)H(24)O(4), a meth­oxy­methyl (MOM) bis-protected BINOL derivative containing a methyl substituent in position 3, is a key inter­mediate for the synthesis of a great variety of chiral auxiliaries. The planes of the naphthyl aromatic rings are at an angle of 70.74 (3)°. There are no conventional hydrogen bonds binding the mol­ecules.
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spelling pubmed-32008322011-11-06 2,2′-Bis(meth­oxy­meth­oxy)-3-methyl-1,1′-binaphth­yl Carrilho, Rui M. B. Abreu, Artur R. Pereira, Mariette M. Rodrigues, V. H. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(25)H(24)O(4), a meth­oxy­methyl (MOM) bis-protected BINOL derivative containing a methyl substituent in position 3, is a key inter­mediate for the synthesis of a great variety of chiral auxiliaries. The planes of the naphthyl aromatic rings are at an angle of 70.74 (3)°. There are no conventional hydrogen bonds binding the mol­ecules. International Union of Crystallography 2011-08-17 /pmc/articles/PMC3200832/ /pubmed/22058976 http://dx.doi.org/10.1107/S1600536811031722 Text en © Carrilho et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Carrilho, Rui M. B.
Abreu, Artur R.
Pereira, Mariette M.
Rodrigues, V. H.
2,2′-Bis(meth­oxy­meth­oxy)-3-methyl-1,1′-binaphth­yl
title 2,2′-Bis(meth­oxy­meth­oxy)-3-methyl-1,1′-binaphth­yl
title_full 2,2′-Bis(meth­oxy­meth­oxy)-3-methyl-1,1′-binaphth­yl
title_fullStr 2,2′-Bis(meth­oxy­meth­oxy)-3-methyl-1,1′-binaphth­yl
title_full_unstemmed 2,2′-Bis(meth­oxy­meth­oxy)-3-methyl-1,1′-binaphth­yl
title_short 2,2′-Bis(meth­oxy­meth­oxy)-3-methyl-1,1′-binaphth­yl
title_sort 2,2′-bis(meth­oxy­meth­oxy)-3-methyl-1,1′-binaphth­yl
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200832/
https://www.ncbi.nlm.nih.gov/pubmed/22058976
http://dx.doi.org/10.1107/S1600536811031722
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