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Dibromido(2,3-di-2-pyridyl­pyrazine-κ(2) N (2),N (3))platinum(II)

The Pt(II) ion in the title complex, [PtBr(2)(C(14)H(10)N(4))], has a slightly distorted square-planar environment defined by the two pyridyl N atoms of the chelating 2,3-di-2-pyridyl­pyrazine ligand and two bromide anions. In the crystal, the pyridyl rings are considerably inclined to the least-squ...

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Autor principal: Ha, Kwang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200834/
https://www.ncbi.nlm.nih.gov/pubmed/22058891
http://dx.doi.org/10.1107/S160053681103412X
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author Ha, Kwang
author_facet Ha, Kwang
author_sort Ha, Kwang
collection PubMed
description The Pt(II) ion in the title complex, [PtBr(2)(C(14)H(10)N(4))], has a slightly distorted square-planar environment defined by the two pyridyl N atoms of the chelating 2,3-di-2-pyridyl­pyrazine ligand and two bromide anions. In the crystal, the pyridyl rings are considerably inclined to the least-squares plane of the PtBr(2)N(2) unit [maximum deviation = 0.064 (2) Å] with dihedral angles of 65.2 (2) and 66.0 (2)°. The nearly planar pyrazine ring [maximum deviation = 0.020 (5) Å] is almost perpendicular to the unit plane with a dihedral angle of 89.2 (2)°. Two independent weak inter­molecular C—H⋯Br hydrogen bonds, both involving the same Br atom as a hydrogen-bond acceptor, give rise to chains running along the a and b axes, forming a layer structure extending parallel to (001). The complexes are stacked in columns along the a axis. When viewed down the b axis, the successive complexes stack in the opposite direction.
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spelling pubmed-32008342011-11-06 Dibromido(2,3-di-2-pyridyl­pyrazine-κ(2) N (2),N (3))platinum(II) Ha, Kwang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Pt(II) ion in the title complex, [PtBr(2)(C(14)H(10)N(4))], has a slightly distorted square-planar environment defined by the two pyridyl N atoms of the chelating 2,3-di-2-pyridyl­pyrazine ligand and two bromide anions. In the crystal, the pyridyl rings are considerably inclined to the least-squares plane of the PtBr(2)N(2) unit [maximum deviation = 0.064 (2) Å] with dihedral angles of 65.2 (2) and 66.0 (2)°. The nearly planar pyrazine ring [maximum deviation = 0.020 (5) Å] is almost perpendicular to the unit plane with a dihedral angle of 89.2 (2)°. Two independent weak inter­molecular C—H⋯Br hydrogen bonds, both involving the same Br atom as a hydrogen-bond acceptor, give rise to chains running along the a and b axes, forming a layer structure extending parallel to (001). The complexes are stacked in columns along the a axis. When viewed down the b axis, the successive complexes stack in the opposite direction. International Union of Crystallography 2011-08-27 /pmc/articles/PMC3200834/ /pubmed/22058891 http://dx.doi.org/10.1107/S160053681103412X Text en © Kwang Ha 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Ha, Kwang
Dibromido(2,3-di-2-pyridyl­pyrazine-κ(2) N (2),N (3))platinum(II)
title Dibromido(2,3-di-2-pyridyl­pyrazine-κ(2) N (2),N (3))platinum(II)
title_full Dibromido(2,3-di-2-pyridyl­pyrazine-κ(2) N (2),N (3))platinum(II)
title_fullStr Dibromido(2,3-di-2-pyridyl­pyrazine-κ(2) N (2),N (3))platinum(II)
title_full_unstemmed Dibromido(2,3-di-2-pyridyl­pyrazine-κ(2) N (2),N (3))platinum(II)
title_short Dibromido(2,3-di-2-pyridyl­pyrazine-κ(2) N (2),N (3))platinum(II)
title_sort dibromido(2,3-di-2-pyridyl­pyrazine-κ(2) n (2),n (3))platinum(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200834/
https://www.ncbi.nlm.nih.gov/pubmed/22058891
http://dx.doi.org/10.1107/S160053681103412X
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