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Dibromido(2,3-di-2-pyridylpyrazine-κ(2) N (2),N (3))platinum(II)
The Pt(II) ion in the title complex, [PtBr(2)(C(14)H(10)N(4))], has a slightly distorted square-planar environment defined by the two pyridyl N atoms of the chelating 2,3-di-2-pyridylpyrazine ligand and two bromide anions. In the crystal, the pyridyl rings are considerably inclined to the least-squ...
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Formato: | Online Artículo Texto |
Lenguaje: | English |
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International Union of Crystallography
2011
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200834/ https://www.ncbi.nlm.nih.gov/pubmed/22058891 http://dx.doi.org/10.1107/S160053681103412X |
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author | Ha, Kwang |
author_facet | Ha, Kwang |
author_sort | Ha, Kwang |
collection | PubMed |
description | The Pt(II) ion in the title complex, [PtBr(2)(C(14)H(10)N(4))], has a slightly distorted square-planar environment defined by the two pyridyl N atoms of the chelating 2,3-di-2-pyridylpyrazine ligand and two bromide anions. In the crystal, the pyridyl rings are considerably inclined to the least-squares plane of the PtBr(2)N(2) unit [maximum deviation = 0.064 (2) Å] with dihedral angles of 65.2 (2) and 66.0 (2)°. The nearly planar pyrazine ring [maximum deviation = 0.020 (5) Å] is almost perpendicular to the unit plane with a dihedral angle of 89.2 (2)°. Two independent weak intermolecular C—H⋯Br hydrogen bonds, both involving the same Br atom as a hydrogen-bond acceptor, give rise to chains running along the a and b axes, forming a layer structure extending parallel to (001). The complexes are stacked in columns along the a axis. When viewed down the b axis, the successive complexes stack in the opposite direction. |
format | Online Article Text |
id | pubmed-3200834 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32008342011-11-06 Dibromido(2,3-di-2-pyridylpyrazine-κ(2) N (2),N (3))platinum(II) Ha, Kwang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Pt(II) ion in the title complex, [PtBr(2)(C(14)H(10)N(4))], has a slightly distorted square-planar environment defined by the two pyridyl N atoms of the chelating 2,3-di-2-pyridylpyrazine ligand and two bromide anions. In the crystal, the pyridyl rings are considerably inclined to the least-squares plane of the PtBr(2)N(2) unit [maximum deviation = 0.064 (2) Å] with dihedral angles of 65.2 (2) and 66.0 (2)°. The nearly planar pyrazine ring [maximum deviation = 0.020 (5) Å] is almost perpendicular to the unit plane with a dihedral angle of 89.2 (2)°. Two independent weak intermolecular C—H⋯Br hydrogen bonds, both involving the same Br atom as a hydrogen-bond acceptor, give rise to chains running along the a and b axes, forming a layer structure extending parallel to (001). The complexes are stacked in columns along the a axis. When viewed down the b axis, the successive complexes stack in the opposite direction. International Union of Crystallography 2011-08-27 /pmc/articles/PMC3200834/ /pubmed/22058891 http://dx.doi.org/10.1107/S160053681103412X Text en © Kwang Ha 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Ha, Kwang Dibromido(2,3-di-2-pyridylpyrazine-κ(2) N (2),N (3))platinum(II) |
title | Dibromido(2,3-di-2-pyridylpyrazine-κ(2)
N
(2),N
(3))platinum(II) |
title_full | Dibromido(2,3-di-2-pyridylpyrazine-κ(2)
N
(2),N
(3))platinum(II) |
title_fullStr | Dibromido(2,3-di-2-pyridylpyrazine-κ(2)
N
(2),N
(3))platinum(II) |
title_full_unstemmed | Dibromido(2,3-di-2-pyridylpyrazine-κ(2)
N
(2),N
(3))platinum(II) |
title_short | Dibromido(2,3-di-2-pyridylpyrazine-κ(2)
N
(2),N
(3))platinum(II) |
title_sort | dibromido(2,3-di-2-pyridylpyrazine-κ(2)
n
(2),n
(3))platinum(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200834/ https://www.ncbi.nlm.nih.gov/pubmed/22058891 http://dx.doi.org/10.1107/S160053681103412X |
work_keys_str_mv | AT hakwang dibromido23di2pyridylpyrazinek2n2n3platinumii |