A double salt of iodo­bis­muthate: cis-aqua­iodidobis(1,10-phenanthroline)cobalt(II) tris­(1,10-phenanthroline)cobalt(II) trans-hexa-μ(2)-iodido-hexa­iodidotribismuthate(III)

In the title complex, [Co(C(12)H(8)N(2))(3)][CoI(C(12)H(8)N(2))(2)(H(2)O)][Bi(3)I(12)], conventionally abbreviated [Co(phen)(3)][CoI(phen)(2)(H(2)O)][Bi(3)I(12)], where phen is 1,10-phenanthroline, the Co(II) atom in one cation is coordinated by six N atoms from three phen ligands in an octa­hedral...

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Autores principales: Chen, Jiongke, Chai, Wenxiang, Song, Li, Yang, Yunyun, Niu, Feng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200835/
https://www.ncbi.nlm.nih.gov/pubmed/22058879
http://dx.doi.org/10.1107/S1600536811033460
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author Chen, Jiongke
Chai, Wenxiang
Song, Li
Yang, Yunyun
Niu, Feng
author_facet Chen, Jiongke
Chai, Wenxiang
Song, Li
Yang, Yunyun
Niu, Feng
author_sort Chen, Jiongke
collection PubMed
description In the title complex, [Co(C(12)H(8)N(2))(3)][CoI(C(12)H(8)N(2))(2)(H(2)O)][Bi(3)I(12)], conventionally abbreviated [Co(phen)(3)][CoI(phen)(2)(H(2)O)][Bi(3)I(12)], where phen is 1,10-phenanthroline, the Co(II) atom in one cation is coordinated by six N atoms from three phen ligands in an octa­hedral coordination while the Co(II) atom in the other cation is coordinated octa­hedrally by four N atoms from two phen ligands, one water O atom and one I atom. In the anion, three Bi(III) ions adopt an octa­hedral coordination constructed by six I(−) ligands. The three BiI(6) octa­hedra are fused together through trans face-sharing.
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spelling pubmed-32008352011-11-06 A double salt of iodo­bis­muthate: cis-aqua­iodidobis(1,10-phenanthroline)cobalt(II) tris­(1,10-phenanthroline)cobalt(II) trans-hexa-μ(2)-iodido-hexa­iodidotribismuthate(III) Chen, Jiongke Chai, Wenxiang Song, Li Yang, Yunyun Niu, Feng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Co(C(12)H(8)N(2))(3)][CoI(C(12)H(8)N(2))(2)(H(2)O)][Bi(3)I(12)], conventionally abbreviated [Co(phen)(3)][CoI(phen)(2)(H(2)O)][Bi(3)I(12)], where phen is 1,10-phenanthroline, the Co(II) atom in one cation is coordinated by six N atoms from three phen ligands in an octa­hedral coordination while the Co(II) atom in the other cation is coordinated octa­hedrally by four N atoms from two phen ligands, one water O atom and one I atom. In the anion, three Bi(III) ions adopt an octa­hedral coordination constructed by six I(−) ligands. The three BiI(6) octa­hedra are fused together through trans face-sharing. International Union of Crystallography 2011-08-27 /pmc/articles/PMC3200835/ /pubmed/22058879 http://dx.doi.org/10.1107/S1600536811033460 Text en © Chen et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Chen, Jiongke
Chai, Wenxiang
Song, Li
Yang, Yunyun
Niu, Feng
A double salt of iodo­bis­muthate: cis-aqua­iodidobis(1,10-phenanthroline)cobalt(II) tris­(1,10-phenanthroline)cobalt(II) trans-hexa-μ(2)-iodido-hexa­iodidotribismuthate(III)
title A double salt of iodo­bis­muthate: cis-aqua­iodidobis(1,10-phenanthroline)cobalt(II) tris­(1,10-phenanthroline)cobalt(II) trans-hexa-μ(2)-iodido-hexa­iodidotribismuthate(III)
title_full A double salt of iodo­bis­muthate: cis-aqua­iodidobis(1,10-phenanthroline)cobalt(II) tris­(1,10-phenanthroline)cobalt(II) trans-hexa-μ(2)-iodido-hexa­iodidotribismuthate(III)
title_fullStr A double salt of iodo­bis­muthate: cis-aqua­iodidobis(1,10-phenanthroline)cobalt(II) tris­(1,10-phenanthroline)cobalt(II) trans-hexa-μ(2)-iodido-hexa­iodidotribismuthate(III)
title_full_unstemmed A double salt of iodo­bis­muthate: cis-aqua­iodidobis(1,10-phenanthroline)cobalt(II) tris­(1,10-phenanthroline)cobalt(II) trans-hexa-μ(2)-iodido-hexa­iodidotribismuthate(III)
title_short A double salt of iodo­bis­muthate: cis-aqua­iodidobis(1,10-phenanthroline)cobalt(II) tris­(1,10-phenanthroline)cobalt(II) trans-hexa-μ(2)-iodido-hexa­iodidotribismuthate(III)
title_sort double salt of iodo­bis­muthate: cis-aqua­iodidobis(1,10-phenanthroline)cobalt(ii) tris­(1,10-phenanthroline)cobalt(ii) trans-hexa-μ(2)-iodido-hexa­iodidotribismuthate(iii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200835/
https://www.ncbi.nlm.nih.gov/pubmed/22058879
http://dx.doi.org/10.1107/S1600536811033460
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