3-Hy­droxy-2-(hy­droxy­meth­yl)pyridinium chloride

The cation of the title compound, C(6)H(8)NO(2) (+)·Cl(−), is essentially planar (r.m.s. deviation = 0.0104 Å). Intermolecular O—H⋯Cl and N—H⋯Cl hydrogen bonds, as well as C—H⋯O contacts, connect the mol­ecules in the crystal structure. A short C⋯C distance of only 3.3930 (19) Å between C atoms of n...

Descripción completa

Detalles Bibliográficos
Autores principales: Betz, Richard, Gerber, Thomas, Hosten, Eric
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200843/
https://www.ncbi.nlm.nih.gov/pubmed/22065694
http://dx.doi.org/10.1107/S1600536811032405
Descripción
Sumario:The cation of the title compound, C(6)H(8)NO(2) (+)·Cl(−), is essentially planar (r.m.s. deviation = 0.0104 Å). Intermolecular O—H⋯Cl and N—H⋯Cl hydrogen bonds, as well as C—H⋯O contacts, connect the mol­ecules in the crystal structure. A short C⋯C distance of only 3.3930 (19) Å between C atoms of neighbouring rings is indicative of π-stacking. The corresponding centroid–centroid distance between the two aromatic systems is 4.2370 (7) Å due to the small overlap of the adjacent rings.

Ejemplares similares