3-Hy­droxy-2-(hy­droxy­meth­yl)pyridinium chloride

The cation of the title compound, C(6)H(8)NO(2) (+)·Cl(−), is essentially planar (r.m.s. deviation = 0.0104 Å). Intermolecular O—H⋯Cl and N—H⋯Cl hydrogen bonds, as well as C—H⋯O contacts, connect the mol­ecules in the crystal structure. A short C⋯C distance of only 3.3930 (19) Å between C atoms of n...

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Detalles Bibliográficos
Autores principales: Betz, Richard, Gerber, Thomas, Hosten, Eric
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200843/
https://www.ncbi.nlm.nih.gov/pubmed/22065694
http://dx.doi.org/10.1107/S1600536811032405
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author Betz, Richard
Gerber, Thomas
Hosten, Eric
author_facet Betz, Richard
Gerber, Thomas
Hosten, Eric
author_sort Betz, Richard
collection PubMed
description The cation of the title compound, C(6)H(8)NO(2) (+)·Cl(−), is essentially planar (r.m.s. deviation = 0.0104 Å). Intermolecular O—H⋯Cl and N—H⋯Cl hydrogen bonds, as well as C—H⋯O contacts, connect the mol­ecules in the crystal structure. A short C⋯C distance of only 3.3930 (19) Å between C atoms of neighbouring rings is indicative of π-stacking. The corresponding centroid–centroid distance between the two aromatic systems is 4.2370 (7) Å due to the small overlap of the adjacent rings.
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spelling pubmed-32008432011-11-06 3-Hy­droxy-2-(hy­droxy­meth­yl)pyridinium chloride Betz, Richard Gerber, Thomas Hosten, Eric Acta Crystallogr Sect E Struct Rep Online Organic Papers The cation of the title compound, C(6)H(8)NO(2) (+)·Cl(−), is essentially planar (r.m.s. deviation = 0.0104 Å). Intermolecular O—H⋯Cl and N—H⋯Cl hydrogen bonds, as well as C—H⋯O contacts, connect the mol­ecules in the crystal structure. A short C⋯C distance of only 3.3930 (19) Å between C atoms of neighbouring rings is indicative of π-stacking. The corresponding centroid–centroid distance between the two aromatic systems is 4.2370 (7) Å due to the small overlap of the adjacent rings. International Union of Crystallography 2011-08-17 /pmc/articles/PMC3200843/ /pubmed/22065694 http://dx.doi.org/10.1107/S1600536811032405 Text en © Betz et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Betz, Richard
Gerber, Thomas
Hosten, Eric
3-Hy­droxy-2-(hy­droxy­meth­yl)pyridinium chloride
title 3-Hy­droxy-2-(hy­droxy­meth­yl)pyridinium chloride
title_full 3-Hy­droxy-2-(hy­droxy­meth­yl)pyridinium chloride
title_fullStr 3-Hy­droxy-2-(hy­droxy­meth­yl)pyridinium chloride
title_full_unstemmed 3-Hy­droxy-2-(hy­droxy­meth­yl)pyridinium chloride
title_short 3-Hy­droxy-2-(hy­droxy­meth­yl)pyridinium chloride
title_sort 3-hy­droxy-2-(hy­droxy­meth­yl)pyridinium chloride
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200843/
https://www.ncbi.nlm.nih.gov/pubmed/22065694
http://dx.doi.org/10.1107/S1600536811032405
work_keys_str_mv AT betzrichard 3hydroxy2hydroxymethylpyridiniumchloride
AT gerberthomas 3hydroxy2hydroxymethylpyridiniumchloride
AT hosteneric 3hydroxy2hydroxymethylpyridiniumchloride

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