Bis(cyanamide-κN)[4-(1H-imidazol-1-yl)phenol-κN (3)]bis­(nitrato-κO)copper(II)

A pair of linear cyanamide (NCNH(2)) ligands, two monodentate 4-(1H-imidazol-1-yl)phenol (L) ligands and two nitrate anions link the Cu(II) atom into a mononuclear unit, [Cu(NO(3))(2)(C(9)H(8)N(2)O)(2)(NCNH(2))(2)]. The coordination polyhedron of the Cu atom is an elongated octa­hedron distorted by...

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Detalles Bibliográficos
Autores principales: Yu, Rui-Jin, Deng, Bin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200852/
https://www.ncbi.nlm.nih.gov/pubmed/22064322
http://dx.doi.org/10.1107/S1600536811032399
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author Yu, Rui-Jin
Deng, Bin
author_facet Yu, Rui-Jin
Deng, Bin
author_sort Yu, Rui-Jin
collection PubMed
description A pair of linear cyanamide (NCNH(2)) ligands, two monodentate 4-(1H-imidazol-1-yl)phenol (L) ligands and two nitrate anions link the Cu(II) atom into a mononuclear unit, [Cu(NO(3))(2)(C(9)H(8)N(2)O)(2)(NCNH(2))(2)]. The coordination polyhedron of the Cu atom is an elongated octa­hedron distorted by Jahn–Teller effects. Inter­molecular O—H⋯O, O—H⋯N, N—H⋯O and N—H⋯N hydrogen-bonding inter­actions link these units into a three-dimensional supra­molecular architecture.
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spelling pubmed-32008522011-11-06 Bis(cyanamide-κN)[4-(1H-imidazol-1-yl)phenol-κN (3)]bis­(nitrato-κO)copper(II) Yu, Rui-Jin Deng, Bin Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers A pair of linear cyanamide (NCNH(2)) ligands, two monodentate 4-(1H-imidazol-1-yl)phenol (L) ligands and two nitrate anions link the Cu(II) atom into a mononuclear unit, [Cu(NO(3))(2)(C(9)H(8)N(2)O)(2)(NCNH(2))(2)]. The coordination polyhedron of the Cu atom is an elongated octa­hedron distorted by Jahn–Teller effects. Inter­molecular O—H⋯O, O—H⋯N, N—H⋯O and N—H⋯N hydrogen-bonding inter­actions link these units into a three-dimensional supra­molecular architecture. International Union of Crystallography 2011-08-17 /pmc/articles/PMC3200852/ /pubmed/22064322 http://dx.doi.org/10.1107/S1600536811032399 Text en © Yu and Deng 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Yu, Rui-Jin
Deng, Bin
Bis(cyanamide-κN)[4-(1H-imidazol-1-yl)phenol-κN (3)]bis­(nitrato-κO)copper(II)
title Bis(cyanamide-κN)[4-(1H-imidazol-1-yl)phenol-κN (3)]bis­(nitrato-κO)copper(II)
title_full Bis(cyanamide-κN)[4-(1H-imidazol-1-yl)phenol-κN (3)]bis­(nitrato-κO)copper(II)
title_fullStr Bis(cyanamide-κN)[4-(1H-imidazol-1-yl)phenol-κN (3)]bis­(nitrato-κO)copper(II)
title_full_unstemmed Bis(cyanamide-κN)[4-(1H-imidazol-1-yl)phenol-κN (3)]bis­(nitrato-κO)copper(II)
title_short Bis(cyanamide-κN)[4-(1H-imidazol-1-yl)phenol-κN (3)]bis­(nitrato-κO)copper(II)
title_sort bis(cyanamide-κn)[4-(1h-imidazol-1-yl)phenol-κn (3)]bis­(nitrato-κo)copper(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200852/
https://www.ncbi.nlm.nih.gov/pubmed/22064322
http://dx.doi.org/10.1107/S1600536811032399
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AT dengbin biscyanamidekn41himidazol1ylphenolkn3bisnitratokocopperii

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