tert-Butyl­aminium 2-carb­oxy-4,5-dichloro­benzoate

In the structure of the title anhydrous salt, C(4)H(12)N(+)·C(8)H(3)Cl(2)O(4) (−), the 4,5-dichloro­phthalate monoanions have the common ‘planar’ conformation with the carboxyl groups close to coplanar with the benzene ring and with a short intra­molecular carb­oxy­lic acid O—H⋯O hydrogen bond. In t...

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Detalles Bibliográficos
Autores principales: Smith, Graham, Wermuth, Urs D.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200858/
https://www.ncbi.nlm.nih.gov/pubmed/22064684
http://dx.doi.org/10.1107/S1600536811034131
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author Smith, Graham
Wermuth, Urs D.
author_facet Smith, Graham
Wermuth, Urs D.
author_sort Smith, Graham
collection PubMed
description In the structure of the title anhydrous salt, C(4)H(12)N(+)·C(8)H(3)Cl(2)O(4) (−), the 4,5-dichloro­phthalate monoanions have the common ‘planar’ conformation with the carboxyl groups close to coplanar with the benzene ring and with a short intra­molecular carb­oxy­lic acid O—H⋯O hydrogen bond. In the crystal, a two-dimensional sheet structure is formed through aminium N—H⋯O(carbox­yl) hydrogen-bonding associations.
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spelling pubmed-32008582011-11-06 tert-Butyl­aminium 2-carb­oxy-4,5-dichloro­benzoate Smith, Graham Wermuth, Urs D. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the structure of the title anhydrous salt, C(4)H(12)N(+)·C(8)H(3)Cl(2)O(4) (−), the 4,5-dichloro­phthalate monoanions have the common ‘planar’ conformation with the carboxyl groups close to coplanar with the benzene ring and with a short intra­molecular carb­oxy­lic acid O—H⋯O hydrogen bond. In the crystal, a two-dimensional sheet structure is formed through aminium N—H⋯O(carbox­yl) hydrogen-bonding associations. International Union of Crystallography 2011-08-27 /pmc/articles/PMC3200858/ /pubmed/22064684 http://dx.doi.org/10.1107/S1600536811034131 Text en © Smith and Wermuth 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Smith, Graham
Wermuth, Urs D.
tert-Butyl­aminium 2-carb­oxy-4,5-dichloro­benzoate
title tert-Butyl­aminium 2-carb­oxy-4,5-dichloro­benzoate
title_full tert-Butyl­aminium 2-carb­oxy-4,5-dichloro­benzoate
title_fullStr tert-Butyl­aminium 2-carb­oxy-4,5-dichloro­benzoate
title_full_unstemmed tert-Butyl­aminium 2-carb­oxy-4,5-dichloro­benzoate
title_short tert-Butyl­aminium 2-carb­oxy-4,5-dichloro­benzoate
title_sort tert-butyl­aminium 2-carb­oxy-4,5-dichloro­benzoate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200858/
https://www.ncbi.nlm.nih.gov/pubmed/22064684
http://dx.doi.org/10.1107/S1600536811034131
work_keys_str_mv AT smithgraham tertbutylaminium2carboxy45dichlorobenzoate
AT wermuthursd tertbutylaminium2carboxy45dichlorobenzoate

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