Triethyl­ammonium 2,4,6-trisulfanylidene-1,3,5-triazinan-1-ide

The asymmetric unit of the title compound, C(6)H(16)N(+)·C(3)H(2)N(3)S(3) (−), contains two independent ion pairs. The 2,4,6-trithioxo-1,3,5-triazinan-1-ide anion features an almost planar six-membered ring (r.m.s. deviations = 0.009 and 0.018 Å) having exocyclic double-bond S atoms. The anions inte...

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Detalles Bibliográficos
Autores principales: Li, He-Ping, Ng, Seik Weng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200860/
https://www.ncbi.nlm.nih.gov/pubmed/22064758
http://dx.doi.org/10.1107/S1600536811034271
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author Li, He-Ping
Ng, Seik Weng
author_facet Li, He-Ping
Ng, Seik Weng
author_sort Li, He-Ping
collection PubMed
description The asymmetric unit of the title compound, C(6)H(16)N(+)·C(3)H(2)N(3)S(3) (−), contains two independent ion pairs. The 2,4,6-trithioxo-1,3,5-triazinan-1-ide anion features an almost planar six-membered ring (r.m.s. deviations = 0.009 and 0.018 Å) having exocyclic double-bond S atoms. The anions inter­act by N—H⋯S hydrogen bonds to generate a chain running along [110]. The triethyl­ammonium cations are hydrogen bonded to the anions with the ammonium H atom forming a hydrogen bond to the negatively-charged N atom of the anion. In the crystal structure, both triethyl­ammonium cations are disordered over two orientations with equal occupancies.
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spelling pubmed-32008602011-11-06 Triethyl­ammonium 2,4,6-trisulfanylidene-1,3,5-triazinan-1-ide Li, He-Ping Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, C(6)H(16)N(+)·C(3)H(2)N(3)S(3) (−), contains two independent ion pairs. The 2,4,6-trithioxo-1,3,5-triazinan-1-ide anion features an almost planar six-membered ring (r.m.s. deviations = 0.009 and 0.018 Å) having exocyclic double-bond S atoms. The anions inter­act by N—H⋯S hydrogen bonds to generate a chain running along [110]. The triethyl­ammonium cations are hydrogen bonded to the anions with the ammonium H atom forming a hydrogen bond to the negatively-charged N atom of the anion. In the crystal structure, both triethyl­ammonium cations are disordered over two orientations with equal occupancies. International Union of Crystallography 2011-08-27 /pmc/articles/PMC3200860/ /pubmed/22064758 http://dx.doi.org/10.1107/S1600536811034271 Text en © Li and Ng 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Li, He-Ping
Ng, Seik Weng
Triethyl­ammonium 2,4,6-trisulfanylidene-1,3,5-triazinan-1-ide
title Triethyl­ammonium 2,4,6-trisulfanylidene-1,3,5-triazinan-1-ide
title_full Triethyl­ammonium 2,4,6-trisulfanylidene-1,3,5-triazinan-1-ide
title_fullStr Triethyl­ammonium 2,4,6-trisulfanylidene-1,3,5-triazinan-1-ide
title_full_unstemmed Triethyl­ammonium 2,4,6-trisulfanylidene-1,3,5-triazinan-1-ide
title_short Triethyl­ammonium 2,4,6-trisulfanylidene-1,3,5-triazinan-1-ide
title_sort triethyl­ammonium 2,4,6-trisulfanylidene-1,3,5-triazinan-1-ide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200860/
https://www.ncbi.nlm.nih.gov/pubmed/22064758
http://dx.doi.org/10.1107/S1600536811034271
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