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(E)-3-[3,4-Bis(methoxymethoxy)phenyl]-1-(7-hydroxy-5-methoxy-2,2-dimethylchroman-8-yl)prop-2-en-1-one
The reaction of 5,6-(2,2-dimethylchromanyl)-2-hydroxy-4-methoxyacetophenone and 3,4-bis(methoxymethyloxy)benzaldehyde affords the intense orange title chalcone derivative, C(25)H(30)O(8). The two benzene rings are connected through a —C(=O)—CH=CH— (propenone) unit, which is in an E conforma...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200863/ https://www.ncbi.nlm.nih.gov/pubmed/22058935 http://dx.doi.org/10.1107/S160053681103131X |
Sumario: | The reaction of 5,6-(2,2-dimethylchromanyl)-2-hydroxy-4-methoxyacetophenone and 3,4-bis(methoxymethyloxy)benzaldehyde affords the intense orange title chalcone derivative, C(25)H(30)O(8). The two benzene rings are connected through a —C(=O)—CH=CH— (propenone) unit, which is in an E conformation; the ring with the hydroxy substitutent is aligned at 19.5 (2)° with respect to this unit, whereas the ring with the methoxymethyloxy substituent is aligned at 9.3 (3)°. The dihedral angle between the rings is 19.38 (10)°. The hydroxy group engages in an intramolecular O—H⋯O hydrogen bond with the carbonyl O atom of the propenone unit, generating an S(5) ring. |
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