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(E)-3-[3,4-Bis(meth­oxy­methoxy)phen­yl]-1-(7-hy­droxy-5-meth­oxy-2,2-dimethyl­chroman-8-yl)prop-2-en-1-one

The reaction of 5,6-(2,2-dimethyl­chroman­yl)-2-hy­droxy-4-meth­oxy­acetophenone and 3,4-bis­(meth­oxy­meth­yloxy)benzaldehyde affords the intense orange title chalcone derivative, C(25)H(30)O(8). The two benzene rings are connected through a —C(=O)—CH=CH— (propenone) unit, which is in an E conforma...

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Detalles Bibliográficos
Autores principales: Hashim, Nur Athirah, Ahmad, Farediah, Basar, Norazah, Awang, Khalijah, Ng, Seik Weng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200863/
https://www.ncbi.nlm.nih.gov/pubmed/22058935
http://dx.doi.org/10.1107/S160053681103131X
Descripción
Sumario:The reaction of 5,6-(2,2-dimethyl­chroman­yl)-2-hy­droxy-4-meth­oxy­acetophenone and 3,4-bis­(meth­oxy­meth­yloxy)benzaldehyde affords the intense orange title chalcone derivative, C(25)H(30)O(8). The two benzene rings are connected through a —C(=O)—CH=CH— (propenone) unit, which is in an E conformation; the ring with the hy­droxy substitutent is aligned at 19.5 (2)° with respect to this unit, whereas the ring with the meth­oxy­meth­yloxy substituent is aligned at 9.3 (3)°. The dihedral angle between the rings is 19.38 (10)°. The hy­droxy group engages in an intra­molecular O—H⋯O hydrogen bond with the carbonyl O atom of the propenone unit, generating an S(5) ring.