Poly[(μ(6)-6-oxidopyridinium-2-carboxyl­ato)caesium]

The asymmetric unit of the polymeric title salt, [Cs(C(6)H(4)NO(3))](n), comprises a Cs(+) cation and a 6-oxidopyridinium-2-carboxyl­ate anion. The Cs(+) cation is six-coordinated by O atoms derived from two oxido and four carboxyl­ate O atoms; each O atom in the anion bridges two Cs(+) cations. In...

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Detalles Bibliográficos
Autores principales: Kang, Sung Kwon, Shim, Yong Suk
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200864/
https://www.ncbi.nlm.nih.gov/pubmed/22064792
http://dx.doi.org/10.1107/S1600536811031874
Descripción
Sumario:The asymmetric unit of the polymeric title salt, [Cs(C(6)H(4)NO(3))](n), comprises a Cs(+) cation and a 6-oxidopyridinium-2-carboxyl­ate anion. The Cs(+) cation is six-coordinated by O atoms derived from two oxido and four carboxyl­ate O atoms; each O atom in the anion bridges two Cs(+) cations. In the crystal, inter­molecular N—H⋯O hydrogen bonding is present and contributes to the stability of the three-dimensional network generated by the bridging O atoms.

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