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1,2-Bis{[3,5-bis­(2,6-diisopropyl­phen­yl)phen­yl]imino}­acenaphthene toluene monosolvate

In the title compound, C(72)H(80)N(2)·C(7)H(8), the acenaphthene ring system is essentially planar, with a maximum deviation of 0.041 (3) Å. The benzene rings bonded to the the N atoms are essentially parallel, forming a dihedral angle of 0.80 (11)°, and these rings form dihedral angles of 87.49 (9)...

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Detalles Bibliográficos
Autores principales: Lohr, Tracy L., Piers, Warren E., Parvez, Masood
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200865/
https://www.ncbi.nlm.nih.gov/pubmed/22058927
http://dx.doi.org/10.1107/S1600536811031242
Descripción
Sumario:In the title compound, C(72)H(80)N(2)·C(7)H(8), the acenaphthene ring system is essentially planar, with a maximum deviation of 0.041 (3) Å. The benzene rings bonded to the the N atoms are essentially parallel, forming a dihedral angle of 0.80 (11)°, and these rings form dihedral angles of 87.49 (9) and 88.25 (10)° with the mean plane of the acenaphthene ring system. The methyl C atoms of three of the isopropyl groups are disordered of two sets of sites of equal occupancy.