Cargando…
8-Hydroxy-2-methylquinolinium tetrachlorido(pyrazine-2-carboxylato-κ(2) N (1),O (2))stannate(IV) methanol monosolvate
In the title solvated salt, (C(10)H(10)NO)[SnCl(4)(C(5)H(3)N(2)O(2))]·CH(3)OH, the Sn(IV) atom is chelated by the N,O-bidentate pyrazine-2-carboxylate ligand and four chloride ions, and shows a distorted octahedral SnNOCl(4) coordination at the metal atom. The 8-hydroxy-2-methylquinolinium catio...
| Autores principales: | , , , |
|---|---|
| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2011
|
| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200866/ https://www.ncbi.nlm.nih.gov/pubmed/22064808 http://dx.doi.org/10.1107/S1600536811032296 |
| _version_ | 1782214767242379264 |
|---|---|
| author | Vafaee, Marzieh Najafi, Ezzatollah Amini, Mostafa M. Ng, Seik Weng |
| author_facet | Vafaee, Marzieh Najafi, Ezzatollah Amini, Mostafa M. Ng, Seik Weng |
| author_sort | Vafaee, Marzieh |
| collection | PubMed |
| description | In the title solvated salt, (C(10)H(10)NO)[SnCl(4)(C(5)H(3)N(2)O(2))]·CH(3)OH, the Sn(IV) atom is chelated by the N,O-bidentate pyrazine-2-carboxylate ligand and four chloride ions, and shows a distorted octahedral SnNOCl(4) coordination at the metal atom. The 8-hydroxy-2-methylquinolinium cation and the anion are linked to the methanol molecules by O—H⋯O, O—H⋯N and N—H⋯O hydrogen bonds, generating a linear chain running along [1[Image: see text]0]. There are two independent ion pairs and solvent molecules in the asymmetric unit. The crystal studied was a non-merohedral twin with a 41.8 (1)% twin component. |
| format | Online Article Text |
| id | pubmed-3200866 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-32008662011-11-06 8-Hydroxy-2-methylquinolinium tetrachlorido(pyrazine-2-carboxylato-κ(2) N (1),O (2))stannate(IV) methanol monosolvate Vafaee, Marzieh Najafi, Ezzatollah Amini, Mostafa M. Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title solvated salt, (C(10)H(10)NO)[SnCl(4)(C(5)H(3)N(2)O(2))]·CH(3)OH, the Sn(IV) atom is chelated by the N,O-bidentate pyrazine-2-carboxylate ligand and four chloride ions, and shows a distorted octahedral SnNOCl(4) coordination at the metal atom. The 8-hydroxy-2-methylquinolinium cation and the anion are linked to the methanol molecules by O—H⋯O, O—H⋯N and N—H⋯O hydrogen bonds, generating a linear chain running along [1[Image: see text]0]. There are two independent ion pairs and solvent molecules in the asymmetric unit. The crystal studied was a non-merohedral twin with a 41.8 (1)% twin component. International Union of Crystallography 2011-08-17 /pmc/articles/PMC3200866/ /pubmed/22064808 http://dx.doi.org/10.1107/S1600536811032296 Text en © Vafaee et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Vafaee, Marzieh Najafi, Ezzatollah Amini, Mostafa M. Ng, Seik Weng 8-Hydroxy-2-methylquinolinium tetrachlorido(pyrazine-2-carboxylato-κ(2) N (1),O (2))stannate(IV) methanol monosolvate |
| title | 8-Hydroxy-2-methylquinolinium tetrachlorido(pyrazine-2-carboxylato-κ(2)
N
(1),O
(2))stannate(IV) methanol monosolvate |
| title_full | 8-Hydroxy-2-methylquinolinium tetrachlorido(pyrazine-2-carboxylato-κ(2)
N
(1),O
(2))stannate(IV) methanol monosolvate |
| title_fullStr | 8-Hydroxy-2-methylquinolinium tetrachlorido(pyrazine-2-carboxylato-κ(2)
N
(1),O
(2))stannate(IV) methanol monosolvate |
| title_full_unstemmed | 8-Hydroxy-2-methylquinolinium tetrachlorido(pyrazine-2-carboxylato-κ(2)
N
(1),O
(2))stannate(IV) methanol monosolvate |
| title_short | 8-Hydroxy-2-methylquinolinium tetrachlorido(pyrazine-2-carboxylato-κ(2)
N
(1),O
(2))stannate(IV) methanol monosolvate |
| title_sort | 8-hydroxy-2-methylquinolinium tetrachlorido(pyrazine-2-carboxylato-κ(2)
n
(1),o
(2))stannate(iv) methanol monosolvate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200866/ https://www.ncbi.nlm.nih.gov/pubmed/22064808 http://dx.doi.org/10.1107/S1600536811032296 |
| work_keys_str_mv | AT vafaeemarzieh 8hydroxy2methylquinoliniumtetrachloridopyrazine2carboxylatok2n1o2stannateivmethanolmonosolvate AT najafiezzatollah 8hydroxy2methylquinoliniumtetrachloridopyrazine2carboxylatok2n1o2stannateivmethanolmonosolvate AT aminimostafam 8hydroxy2methylquinoliniumtetrachloridopyrazine2carboxylatok2n1o2stannateivmethanolmonosolvate AT ngseikweng 8hydroxy2methylquinoliniumtetrachloridopyrazine2carboxylatok2n1o2stannateivmethanolmonosolvate |