μ-Acetato-diacetato{μ-6,6′-dimethoxy-2,2′-[o-phenylenebis(nitrilomethanylylidene)]diphenolato}gadolinium(III)zinc

In the heterodinuclear title complex, [GdZn(C(22)H(18)N(2)O(4))(CH(3)COO)(3)], the Zn(II) ion is five-coordinated in a square-pyramidal environment defined by two O atoms and two N atoms from the ligand, forming the square plane, and one acetate O atom serving as the apex, while the Gd(III) ion is n...

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Detalles Bibliográficos
Autores principales: Yang, Fan, Li, Guang-Ming, Chen, Peng, Yan, Peng-Fei, Hou, Guang-Feng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200867/
https://www.ncbi.nlm.nih.gov/pubmed/22058837
http://dx.doi.org/10.1107/S160053681102890X
Descripción
Sumario:In the heterodinuclear title complex, [GdZn(C(22)H(18)N(2)O(4))(CH(3)COO)(3)], the Zn(II) ion is five-coordinated in a square-pyramidal environment defined by two O atoms and two N atoms from the ligand, forming the square plane, and one acetate O atom serving as the apex, while the Gd(III) ion is nine-coordinated in an approximate mono-capped tetra­gonal–anti­prismatic environment defined by four O atoms from the ligand and five acetate O atoms.

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