μ-Acetato-diacetato{μ-6,6′-dimethoxy-2,2′-[o-phenylenebis(nitrilomethanylylidene)]diphenolato}gadolinium(III)zinc

In the heterodinuclear title complex, [GdZn(C(22)H(18)N(2)O(4))(CH(3)COO)(3)], the Zn(II) ion is five-coordinated in a square-pyramidal environment defined by two O atoms and two N atoms from the ligand, forming the square plane, and one acetate O atom serving as the apex, while the Gd(III) ion is n...

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Detalles Bibliográficos
Autores principales: Yang, Fan, Li, Guang-Ming, Chen, Peng, Yan, Peng-Fei, Hou, Guang-Feng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200867/
https://www.ncbi.nlm.nih.gov/pubmed/22058837
http://dx.doi.org/10.1107/S160053681102890X
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author Yang, Fan
Li, Guang-Ming
Chen, Peng
Yan, Peng-Fei
Hou, Guang-Feng
author_facet Yang, Fan
Li, Guang-Ming
Chen, Peng
Yan, Peng-Fei
Hou, Guang-Feng
author_sort Yang, Fan
collection PubMed
description In the heterodinuclear title complex, [GdZn(C(22)H(18)N(2)O(4))(CH(3)COO)(3)], the Zn(II) ion is five-coordinated in a square-pyramidal environment defined by two O atoms and two N atoms from the ligand, forming the square plane, and one acetate O atom serving as the apex, while the Gd(III) ion is nine-coordinated in an approximate mono-capped tetra­gonal–anti­prismatic environment defined by four O atoms from the ligand and five acetate O atoms.
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spelling pubmed-32008672011-11-06 μ-Acetato-diacetato{μ-6,6′-dimethoxy-2,2′-[o-phenylenebis(nitrilomethanylylidene)]diphenolato}gadolinium(III)zinc Yang, Fan Li, Guang-Ming Chen, Peng Yan, Peng-Fei Hou, Guang-Feng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the heterodinuclear title complex, [GdZn(C(22)H(18)N(2)O(4))(CH(3)COO)(3)], the Zn(II) ion is five-coordinated in a square-pyramidal environment defined by two O atoms and two N atoms from the ligand, forming the square plane, and one acetate O atom serving as the apex, while the Gd(III) ion is nine-coordinated in an approximate mono-capped tetra­gonal–anti­prismatic environment defined by four O atoms from the ligand and five acetate O atoms. International Union of Crystallography 2011-08-02 /pmc/articles/PMC3200867/ /pubmed/22058837 http://dx.doi.org/10.1107/S160053681102890X Text en © Yang et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Yang, Fan
Li, Guang-Ming
Chen, Peng
Yan, Peng-Fei
Hou, Guang-Feng
μ-Acetato-diacetato{μ-6,6′-dimethoxy-2,2′-[o-phenylenebis(nitrilomethanylylidene)]diphenolato}gadolinium(III)zinc
title μ-Acetato-diacetato{μ-6,6′-dimethoxy-2,2′-[o-phenylenebis(nitrilomethanylylidene)]diphenolato}gadolinium(III)zinc
title_full μ-Acetato-diacetato{μ-6,6′-dimethoxy-2,2′-[o-phenylenebis(nitrilomethanylylidene)]diphenolato}gadolinium(III)zinc
title_fullStr μ-Acetato-diacetato{μ-6,6′-dimethoxy-2,2′-[o-phenylenebis(nitrilomethanylylidene)]diphenolato}gadolinium(III)zinc
title_full_unstemmed μ-Acetato-diacetato{μ-6,6′-dimethoxy-2,2′-[o-phenylenebis(nitrilomethanylylidene)]diphenolato}gadolinium(III)zinc
title_short μ-Acetato-diacetato{μ-6,6′-dimethoxy-2,2′-[o-phenylenebis(nitrilomethanylylidene)]diphenolato}gadolinium(III)zinc
title_sort μ-acetato-diacetato{μ-6,6′-dimethoxy-2,2′-[o-phenylenebis(nitrilomethanylylidene)]diphenolato}gadolinium(iii)zinc
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200867/
https://www.ncbi.nlm.nih.gov/pubmed/22058837
http://dx.doi.org/10.1107/S160053681102890X
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