(Penta­fluoro­propionato-κO)tetra­kis­(trimethyl­phosphine oxide-κO)copper(II) penta­fluoro­propionate

The title compound, [Cu(C(3)F(5)O(2))(C(3)H(9)OP)(4)](C(3)F(5)O(2)), comprises a cationic Cu(II) complex and a disordered penta­fluoro­propionate counter-ion. The metal atom has a distorted square-pyramidal coordination environment formed by four O atoms originating from trimethyl­phosphine oxide mo...

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Detalles Bibliográficos
Autores principales: Szymańska, Iwona B., Dobrzańska, Liliana
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200869/
https://www.ncbi.nlm.nih.gov/pubmed/22064902
http://dx.doi.org/10.1107/S1600536811031114
Descripción
Sumario:The title compound, [Cu(C(3)F(5)O(2))(C(3)H(9)OP)(4)](C(3)F(5)O(2)), comprises a cationic Cu(II) complex and a disordered penta­fluoro­propionate counter-ion. The metal atom has a distorted square-pyramidal coordination environment formed by four O atoms originating from trimethyl­phosphine oxide mol­ecules and the remaining one belonging to the monodentate penta­fluoro­propionate anion, which is situated in the basal plane of the pyramid. The mol­ecules are held together in the crystal by a net of weak C—H⋯O and C—H⋯F hydrogen bonds. The counter anion is disordered over two sets of sites in a 0.629 (5):0.371 (5) ratio.

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