(Penta­fluoro­propionato-κO)tetra­kis­(trimethyl­phosphine oxide-κO)copper(II) penta­fluoro­propionate

The title compound, [Cu(C(3)F(5)O(2))(C(3)H(9)OP)(4)](C(3)F(5)O(2)), comprises a cationic Cu(II) complex and a disordered penta­fluoro­propionate counter-ion. The metal atom has a distorted square-pyramidal coordination environment formed by four O atoms originating from trimethyl­phosphine oxide mo...

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Detalles Bibliográficos
Autores principales: Szymańska, Iwona B., Dobrzańska, Liliana
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200869/
https://www.ncbi.nlm.nih.gov/pubmed/22064902
http://dx.doi.org/10.1107/S1600536811031114
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author Szymańska, Iwona B.
Dobrzańska, Liliana
author_facet Szymańska, Iwona B.
Dobrzańska, Liliana
author_sort Szymańska, Iwona B.
collection PubMed
description The title compound, [Cu(C(3)F(5)O(2))(C(3)H(9)OP)(4)](C(3)F(5)O(2)), comprises a cationic Cu(II) complex and a disordered penta­fluoro­propionate counter-ion. The metal atom has a distorted square-pyramidal coordination environment formed by four O atoms originating from trimethyl­phosphine oxide mol­ecules and the remaining one belonging to the monodentate penta­fluoro­propionate anion, which is situated in the basal plane of the pyramid. The mol­ecules are held together in the crystal by a net of weak C—H⋯O and C—H⋯F hydrogen bonds. The counter anion is disordered over two sets of sites in a 0.629 (5):0.371 (5) ratio.
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spelling pubmed-32008692011-11-06 (Penta­fluoro­propionato-κO)tetra­kis­(trimethyl­phosphine oxide-κO)copper(II) penta­fluoro­propionate Szymańska, Iwona B. Dobrzańska, Liliana Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Cu(C(3)F(5)O(2))(C(3)H(9)OP)(4)](C(3)F(5)O(2)), comprises a cationic Cu(II) complex and a disordered penta­fluoro­propionate counter-ion. The metal atom has a distorted square-pyramidal coordination environment formed by four O atoms originating from trimethyl­phosphine oxide mol­ecules and the remaining one belonging to the monodentate penta­fluoro­propionate anion, which is situated in the basal plane of the pyramid. The mol­ecules are held together in the crystal by a net of weak C—H⋯O and C—H⋯F hydrogen bonds. The counter anion is disordered over two sets of sites in a 0.629 (5):0.371 (5) ratio. International Union of Crystallography 2011-08-11 /pmc/articles/PMC3200869/ /pubmed/22064902 http://dx.doi.org/10.1107/S1600536811031114 Text en © Szymańska and Dobrzańska 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Szymańska, Iwona B.
Dobrzańska, Liliana
(Penta­fluoro­propionato-κO)tetra­kis­(trimethyl­phosphine oxide-κO)copper(II) penta­fluoro­propionate
title (Penta­fluoro­propionato-κO)tetra­kis­(trimethyl­phosphine oxide-κO)copper(II) penta­fluoro­propionate
title_full (Penta­fluoro­propionato-κO)tetra­kis­(trimethyl­phosphine oxide-κO)copper(II) penta­fluoro­propionate
title_fullStr (Penta­fluoro­propionato-κO)tetra­kis­(trimethyl­phosphine oxide-κO)copper(II) penta­fluoro­propionate
title_full_unstemmed (Penta­fluoro­propionato-κO)tetra­kis­(trimethyl­phosphine oxide-κO)copper(II) penta­fluoro­propionate
title_short (Penta­fluoro­propionato-κO)tetra­kis­(trimethyl­phosphine oxide-κO)copper(II) penta­fluoro­propionate
title_sort (penta­fluoro­propionato-κo)tetra­kis­(trimethyl­phosphine oxide-κo)copper(ii) penta­fluoro­propionate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200869/
https://www.ncbi.nlm.nih.gov/pubmed/22064902
http://dx.doi.org/10.1107/S1600536811031114
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AT dobrzanskaliliana pentafluoropropionatokotetrakistrimethylphosphineoxidekocopperiipentafluoropropionate

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