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catena-Poly[[triphenyl­tin(IV)]-μ-5-amino-2-nitro­benzoato-κ(2) O (1):O (1′)]

The title compound, [Sn(C(6)H(5))(3)(C(7)H(5)N(2)O(4))](n), forms polymeric chains along [010]. The Sn(IV) ion is five-coordinated in a distorted trigonal–bipyramidal geometry by two monodentate carboxyl­ate groups and three phenyl rings. The axial sites are occupied by the O atoms of two symmetry-r...

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Autores principales: Win, Yip-Foo, Choong, Chen-Shang, Teoh, Siang-Guan, Quah, Ching Kheng, Fun, Hoong-Kun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200871/
https://www.ncbi.nlm.nih.gov/pubmed/22064934
http://dx.doi.org/10.1107/S1600536811033332
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author Win, Yip-Foo
Choong, Chen-Shang
Teoh, Siang-Guan
Quah, Ching Kheng
Fun, Hoong-Kun
author_facet Win, Yip-Foo
Choong, Chen-Shang
Teoh, Siang-Guan
Quah, Ching Kheng
Fun, Hoong-Kun
author_sort Win, Yip-Foo
collection PubMed
description The title compound, [Sn(C(6)H(5))(3)(C(7)H(5)N(2)O(4))](n), forms polymeric chains along [010]. The Sn(IV) ion is five-coordinated in a distorted trigonal–bipyramidal geometry by two monodentate carboxyl­ate groups and three phenyl rings. The axial sites are occupied by the O atoms of two symmetry-related carboxyl­ate groups [O—Sn—O = 170.88 (3)°]. The benzene ring of the 5-amino-2-nitro­benzoate ligand forms dihedral angles of 82.92 (6), 81.10 (6) and 83.54 (6)° with respect to the three phenyl rings. In the crystal, the chains are linked by inter­molecular N—H⋯O and weak C—H⋯O inter­actions into a three-dimensional network. The crystal structure is further stabilized by weak inter­molecular C—H⋯π inter­actions.
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spelling pubmed-32008712011-11-06 catena-Poly[[triphenyl­tin(IV)]-μ-5-amino-2-nitro­benzoato-κ(2) O (1):O (1′)] Win, Yip-Foo Choong, Chen-Shang Teoh, Siang-Guan Quah, Ching Kheng Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Sn(C(6)H(5))(3)(C(7)H(5)N(2)O(4))](n), forms polymeric chains along [010]. The Sn(IV) ion is five-coordinated in a distorted trigonal–bipyramidal geometry by two monodentate carboxyl­ate groups and three phenyl rings. The axial sites are occupied by the O atoms of two symmetry-related carboxyl­ate groups [O—Sn—O = 170.88 (3)°]. The benzene ring of the 5-amino-2-nitro­benzoate ligand forms dihedral angles of 82.92 (6), 81.10 (6) and 83.54 (6)° with respect to the three phenyl rings. In the crystal, the chains are linked by inter­molecular N—H⋯O and weak C—H⋯O inter­actions into a three-dimensional network. The crystal structure is further stabilized by weak inter­molecular C—H⋯π inter­actions. International Union of Crystallography 2011-08-27 /pmc/articles/PMC3200871/ /pubmed/22064934 http://dx.doi.org/10.1107/S1600536811033332 Text en © Win et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Win, Yip-Foo
Choong, Chen-Shang
Teoh, Siang-Guan
Quah, Ching Kheng
Fun, Hoong-Kun
catena-Poly[[triphenyl­tin(IV)]-μ-5-amino-2-nitro­benzoato-κ(2) O (1):O (1′)]
title catena-Poly[[triphenyl­tin(IV)]-μ-5-amino-2-nitro­benzoato-κ(2) O (1):O (1′)]
title_full catena-Poly[[triphenyl­tin(IV)]-μ-5-amino-2-nitro­benzoato-κ(2) O (1):O (1′)]
title_fullStr catena-Poly[[triphenyl­tin(IV)]-μ-5-amino-2-nitro­benzoato-κ(2) O (1):O (1′)]
title_full_unstemmed catena-Poly[[triphenyl­tin(IV)]-μ-5-amino-2-nitro­benzoato-κ(2) O (1):O (1′)]
title_short catena-Poly[[triphenyl­tin(IV)]-μ-5-amino-2-nitro­benzoato-κ(2) O (1):O (1′)]
title_sort catena-poly[[triphenyl­tin(iv)]-μ-5-amino-2-nitro­benzoato-κ(2) o (1):o (1′)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200871/
https://www.ncbi.nlm.nih.gov/pubmed/22064934
http://dx.doi.org/10.1107/S1600536811033332
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