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catena-Poly[[triphenyltin(IV)]-μ-5-amino-2-nitrobenzoato-κ(2) O (1):O (1′)]
The title compound, [Sn(C(6)H(5))(3)(C(7)H(5)N(2)O(4))](n), forms polymeric chains along [010]. The Sn(IV) ion is five-coordinated in a distorted trigonal–bipyramidal geometry by two monodentate carboxylate groups and three phenyl rings. The axial sites are occupied by the O atoms of two symmetry-r...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200871/ https://www.ncbi.nlm.nih.gov/pubmed/22064934 http://dx.doi.org/10.1107/S1600536811033332 |
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author | Win, Yip-Foo Choong, Chen-Shang Teoh, Siang-Guan Quah, Ching Kheng Fun, Hoong-Kun |
author_facet | Win, Yip-Foo Choong, Chen-Shang Teoh, Siang-Guan Quah, Ching Kheng Fun, Hoong-Kun |
author_sort | Win, Yip-Foo |
collection | PubMed |
description | The title compound, [Sn(C(6)H(5))(3)(C(7)H(5)N(2)O(4))](n), forms polymeric chains along [010]. The Sn(IV) ion is five-coordinated in a distorted trigonal–bipyramidal geometry by two monodentate carboxylate groups and three phenyl rings. The axial sites are occupied by the O atoms of two symmetry-related carboxylate groups [O—Sn—O = 170.88 (3)°]. The benzene ring of the 5-amino-2-nitrobenzoate ligand forms dihedral angles of 82.92 (6), 81.10 (6) and 83.54 (6)° with respect to the three phenyl rings. In the crystal, the chains are linked by intermolecular N—H⋯O and weak C—H⋯O interactions into a three-dimensional network. The crystal structure is further stabilized by weak intermolecular C—H⋯π interactions. |
format | Online Article Text |
id | pubmed-3200871 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32008712011-11-06 catena-Poly[[triphenyltin(IV)]-μ-5-amino-2-nitrobenzoato-κ(2) O (1):O (1′)] Win, Yip-Foo Choong, Chen-Shang Teoh, Siang-Guan Quah, Ching Kheng Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Sn(C(6)H(5))(3)(C(7)H(5)N(2)O(4))](n), forms polymeric chains along [010]. The Sn(IV) ion is five-coordinated in a distorted trigonal–bipyramidal geometry by two monodentate carboxylate groups and three phenyl rings. The axial sites are occupied by the O atoms of two symmetry-related carboxylate groups [O—Sn—O = 170.88 (3)°]. The benzene ring of the 5-amino-2-nitrobenzoate ligand forms dihedral angles of 82.92 (6), 81.10 (6) and 83.54 (6)° with respect to the three phenyl rings. In the crystal, the chains are linked by intermolecular N—H⋯O and weak C—H⋯O interactions into a three-dimensional network. The crystal structure is further stabilized by weak intermolecular C—H⋯π interactions. International Union of Crystallography 2011-08-27 /pmc/articles/PMC3200871/ /pubmed/22064934 http://dx.doi.org/10.1107/S1600536811033332 Text en © Win et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Win, Yip-Foo Choong, Chen-Shang Teoh, Siang-Guan Quah, Ching Kheng Fun, Hoong-Kun catena-Poly[[triphenyltin(IV)]-μ-5-amino-2-nitrobenzoato-κ(2) O (1):O (1′)] |
title |
catena-Poly[[triphenyltin(IV)]-μ-5-amino-2-nitrobenzoato-κ(2)
O
(1):O
(1′)] |
title_full |
catena-Poly[[triphenyltin(IV)]-μ-5-amino-2-nitrobenzoato-κ(2)
O
(1):O
(1′)] |
title_fullStr |
catena-Poly[[triphenyltin(IV)]-μ-5-amino-2-nitrobenzoato-κ(2)
O
(1):O
(1′)] |
title_full_unstemmed |
catena-Poly[[triphenyltin(IV)]-μ-5-amino-2-nitrobenzoato-κ(2)
O
(1):O
(1′)] |
title_short |
catena-Poly[[triphenyltin(IV)]-μ-5-amino-2-nitrobenzoato-κ(2)
O
(1):O
(1′)] |
title_sort | catena-poly[[triphenyltin(iv)]-μ-5-amino-2-nitrobenzoato-κ(2)
o
(1):o
(1′)] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200871/ https://www.ncbi.nlm.nih.gov/pubmed/22064934 http://dx.doi.org/10.1107/S1600536811033332 |
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