3-(2-Bromo­phen­yl)thia­zolo[3,2-a]benzimidazole

The title compound, C(15)H(9)BrN(2)S, was prepared by the reaction of 1-bromo-2-(2,2-dibromo­vin­yl)benzene with 1H-benzo[d]imidazole-2(3H)-thione. The thia­zolo[3,2-a]benz­imidazole fused-ring system is nearly planar, the maximum atomic deviation being 0.049 (4) Å. This mean plane is oriented at a...

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Detalles Bibliográficos
Autores principales: Wang, Zhi-Ming, Yu, Bin, Cui, Yuan, Zhang, Xiu-Qing, Sun, Xiao-Qiang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200872/
https://www.ncbi.nlm.nih.gov/pubmed/22065022
http://dx.doi.org/10.1107/S1600536811034842
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author Wang, Zhi-Ming
Yu, Bin
Cui, Yuan
Zhang, Xiu-Qing
Sun, Xiao-Qiang
author_facet Wang, Zhi-Ming
Yu, Bin
Cui, Yuan
Zhang, Xiu-Qing
Sun, Xiao-Qiang
author_sort Wang, Zhi-Ming
collection PubMed
description The title compound, C(15)H(9)BrN(2)S, was prepared by the reaction of 1-bromo-2-(2,2-dibromo­vin­yl)benzene with 1H-benzo[d]imidazole-2(3H)-thione. The thia­zolo[3,2-a]benz­imidazole fused-ring system is nearly planar, the maximum atomic deviation being 0.049 (4) Å. This mean plane is oriented at a dihedral angle of 71.55 (17)° with respect ot the bromo­phenyl ring. π–π stacking is observed in the crystal structure, the centroid–centroid distance between the thia­zole and imidazole rings of adjacent mol­ecules being 3.582 (2) Å.
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spelling pubmed-32008722011-11-06 3-(2-Bromo­phen­yl)thia­zolo[3,2-a]benzimidazole Wang, Zhi-Ming Yu, Bin Cui, Yuan Zhang, Xiu-Qing Sun, Xiao-Qiang Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(15)H(9)BrN(2)S, was prepared by the reaction of 1-bromo-2-(2,2-dibromo­vin­yl)benzene with 1H-benzo[d]imidazole-2(3H)-thione. The thia­zolo[3,2-a]benz­imidazole fused-ring system is nearly planar, the maximum atomic deviation being 0.049 (4) Å. This mean plane is oriented at a dihedral angle of 71.55 (17)° with respect ot the bromo­phenyl ring. π–π stacking is observed in the crystal structure, the centroid–centroid distance between the thia­zole and imidazole rings of adjacent mol­ecules being 3.582 (2) Å. International Union of Crystallography 2011-08-31 /pmc/articles/PMC3200872/ /pubmed/22065022 http://dx.doi.org/10.1107/S1600536811034842 Text en © Wang et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Wang, Zhi-Ming
Yu, Bin
Cui, Yuan
Zhang, Xiu-Qing
Sun, Xiao-Qiang
3-(2-Bromo­phen­yl)thia­zolo[3,2-a]benzimidazole
title 3-(2-Bromo­phen­yl)thia­zolo[3,2-a]benzimidazole
title_full 3-(2-Bromo­phen­yl)thia­zolo[3,2-a]benzimidazole
title_fullStr 3-(2-Bromo­phen­yl)thia­zolo[3,2-a]benzimidazole
title_full_unstemmed 3-(2-Bromo­phen­yl)thia­zolo[3,2-a]benzimidazole
title_short 3-(2-Bromo­phen­yl)thia­zolo[3,2-a]benzimidazole
title_sort 3-(2-bromo­phen­yl)thia­zolo[3,2-a]benzimidazole
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200872/
https://www.ncbi.nlm.nih.gov/pubmed/22065022
http://dx.doi.org/10.1107/S1600536811034842
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AT cuiyuan 32bromophenylthiazolo32abenzimidazole
AT zhangxiuqing 32bromophenylthiazolo32abenzimidazole
AT sunxiaoqiang 32bromophenylthiazolo32abenzimidazole

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