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N-[4-(Ethyl­sulfamo­yl)phen­yl]acetamide

The title compound, C(10)H(14)N(2)O(3)S, crystallized with two mol­ecules (A and B) in the asymmetric unit. The terminal methyl group of the ethyl­sulfonamide moiety in mol­ecule B is disordered over two sets of sites with an occupancy ratio of 0.61 (1):0.39 (1). Both mol­ecules have L-shaped confor...

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Detalles Bibliográficos
Autores principales: Rehman, Jeveria, Ejaz, Khan, Islam Ullah, Harrison, William T. A., Farid, Sidra
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200875/
https://www.ncbi.nlm.nih.gov/pubmed/22059023
http://dx.doi.org/10.1107/S1600536811033472
Descripción
Sumario:The title compound, C(10)H(14)N(2)O(3)S, crystallized with two mol­ecules (A and B) in the asymmetric unit. The terminal methyl group of the ethyl­sulfonamide moiety in mol­ecule B is disordered over two sets of sites with an occupancy ratio of 0.61 (1):0.39 (1). Both mol­ecules have L-shaped conformations. In mol­ecule A, the dihedral angles between the benzene ring and its ethyl­sulfonamide and methyl­amide substituents are 83.5 (3) and 13.34 (18)°, respectively. Equivalent values for mol­ecule B are 87.9 (3) and 6.32 (16)°, respectively. The C—S—N—C torsion angles are 66.5 (3)° for A and −64.4 (3)° for B, indicating similar twists about the S—N bonds, but in opposite senses. In the crystal, the A mol­ecules are linked by pairs of N(s)—H⋯O (s = sulfonamide) hydrogen bonds, generating inversion dimers containing R (2) (2)(8) rings, while the B mol­ecules are linked by N(s)—H⋯O hydrogen bonds into C(10) [100] chains. Finally, N(a)—H⋯O (a = amide) hydrogen bonds link the A-mol­ecule dimers and B-mol­ecule chains into a three-dimensional network.