Cargando…
Aqua[4-(hydroxyiminomethyl)pyridine-κN (1)](iminodiacetato-κ(3) O,N,O′)copper(II)
In the title complex, [Cu(C(4)H(5)NO(4))(C(6)H(6)N(2)O)(H(2)O)], conventionally abbreviated Cu(IDA)(4-OXPy)(H(2)O), where IDA is iminodiacetate and 4-OXPy is 4-(hydroxyiminomethyl)pyridine, the Cu(II) atom exhibits a distorted square-pyramidal coordination geometry, which is constructed from tw...
Autores principales: | , , , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200882/ https://www.ncbi.nlm.nih.gov/pubmed/22065407 http://dx.doi.org/10.1107/S1600536811033459 |
_version_ | 1782214770867306496 |
---|---|
author | Yang, Yisheng Chai, Wenxiang Song, Li Yang, Yunyun Chen, Jiongke |
author_facet | Yang, Yisheng Chai, Wenxiang Song, Li Yang, Yunyun Chen, Jiongke |
author_sort | Yang, Yisheng |
collection | PubMed |
description | In the title complex, [Cu(C(4)H(5)NO(4))(C(6)H(6)N(2)O)(H(2)O)], conventionally abbreviated Cu(IDA)(4-OXPy)(H(2)O), where IDA is iminodiacetate and 4-OXPy is 4-(hydroxyiminomethyl)pyridine, the Cu(II) atom exhibits a distorted square-pyramidal coordination geometry, which is constructed from two O atoms and one N atom from a IDA ligand, one N atom from 4-OXPy ligand and one O atom from water. This molecule looks like a space shuttle, the IDA ligand is its empennage (tail), and the 4-OXPy ligand is its airframe. The complexes are linked into two-dimensional supramolecular layers parallel to (100) by three pairs of O—H⋯O hydrogen bonds. Two pairs of N—H⋯O hydrogen bonds further connect these supramolecular layers, forming a three-dimensional supramolecular network. |
format | Online Article Text |
id | pubmed-3200882 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32008822011-11-06 Aqua[4-(hydroxyiminomethyl)pyridine-κN (1)](iminodiacetato-κ(3) O,N,O′)copper(II) Yang, Yisheng Chai, Wenxiang Song, Li Yang, Yunyun Chen, Jiongke Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Cu(C(4)H(5)NO(4))(C(6)H(6)N(2)O)(H(2)O)], conventionally abbreviated Cu(IDA)(4-OXPy)(H(2)O), where IDA is iminodiacetate and 4-OXPy is 4-(hydroxyiminomethyl)pyridine, the Cu(II) atom exhibits a distorted square-pyramidal coordination geometry, which is constructed from two O atoms and one N atom from a IDA ligand, one N atom from 4-OXPy ligand and one O atom from water. This molecule looks like a space shuttle, the IDA ligand is its empennage (tail), and the 4-OXPy ligand is its airframe. The complexes are linked into two-dimensional supramolecular layers parallel to (100) by three pairs of O—H⋯O hydrogen bonds. Two pairs of N—H⋯O hydrogen bonds further connect these supramolecular layers, forming a three-dimensional supramolecular network. International Union of Crystallography 2011-08-27 /pmc/articles/PMC3200882/ /pubmed/22065407 http://dx.doi.org/10.1107/S1600536811033459 Text en © Yang et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Yang, Yisheng Chai, Wenxiang Song, Li Yang, Yunyun Chen, Jiongke Aqua[4-(hydroxyiminomethyl)pyridine-κN (1)](iminodiacetato-κ(3) O,N,O′)copper(II) |
title | Aqua[4-(hydroxyiminomethyl)pyridine-κN
(1)](iminodiacetato-κ(3)
O,N,O′)copper(II) |
title_full | Aqua[4-(hydroxyiminomethyl)pyridine-κN
(1)](iminodiacetato-κ(3)
O,N,O′)copper(II) |
title_fullStr | Aqua[4-(hydroxyiminomethyl)pyridine-κN
(1)](iminodiacetato-κ(3)
O,N,O′)copper(II) |
title_full_unstemmed | Aqua[4-(hydroxyiminomethyl)pyridine-κN
(1)](iminodiacetato-κ(3)
O,N,O′)copper(II) |
title_short | Aqua[4-(hydroxyiminomethyl)pyridine-κN
(1)](iminodiacetato-κ(3)
O,N,O′)copper(II) |
title_sort | aqua[4-(hydroxyiminomethyl)pyridine-κn
(1)](iminodiacetato-κ(3)
o,n,o′)copper(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200882/ https://www.ncbi.nlm.nih.gov/pubmed/22065407 http://dx.doi.org/10.1107/S1600536811033459 |
work_keys_str_mv | AT yangyisheng aqua4hydroxyiminomethylpyridinekn1iminodiacetatok3onocopperii AT chaiwenxiang aqua4hydroxyiminomethylpyridinekn1iminodiacetatok3onocopperii AT songli aqua4hydroxyiminomethylpyridinekn1iminodiacetatok3onocopperii AT yangyunyun aqua4hydroxyiminomethylpyridinekn1iminodiacetatok3onocopperii AT chenjiongke aqua4hydroxyiminomethylpyridinekn1iminodiacetatok3onocopperii |