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Aqua­[4-(hy­droxy­imino­meth­yl)pyridine-κN (1)](imino­diacetato-κ(3) O,N,O′)copper(II)

In the title complex, [Cu(C(4)H(5)NO(4))(C(6)H(6)N(2)O)(H(2)O)], conventionally abbreviated Cu(IDA)(4-OXPy)(H(2)O), where IDA is imino­diacetate and 4-OXPy is 4-(hy­droxy­imino­meth­yl)pyridine, the Cu(II) atom exhibits a distorted square-pyramidal coordination geometry, which is constructed from tw...

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Autores principales: Yang, Yisheng, Chai, Wenxiang, Song, Li, Yang, Yunyun, Chen, Jiongke
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200882/
https://www.ncbi.nlm.nih.gov/pubmed/22065407
http://dx.doi.org/10.1107/S1600536811033459
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author Yang, Yisheng
Chai, Wenxiang
Song, Li
Yang, Yunyun
Chen, Jiongke
author_facet Yang, Yisheng
Chai, Wenxiang
Song, Li
Yang, Yunyun
Chen, Jiongke
author_sort Yang, Yisheng
collection PubMed
description In the title complex, [Cu(C(4)H(5)NO(4))(C(6)H(6)N(2)O)(H(2)O)], conventionally abbreviated Cu(IDA)(4-OXPy)(H(2)O), where IDA is imino­diacetate and 4-OXPy is 4-(hy­droxy­imino­meth­yl)pyridine, the Cu(II) atom exhibits a distorted square-pyramidal coordination geometry, which is constructed from two O atoms and one N atom from a IDA ligand, one N atom from 4-OXPy ligand and one O atom from water. This mol­ecule looks like a space shuttle, the IDA ligand is its empennage (tail), and the 4-OXPy ligand is its airframe. The complexes are linked into two-dimensional supra­molecular layers parallel to (100) by three pairs of O—H⋯O hydrogen bonds. Two pairs of N—H⋯O hydrogen bonds further connect these supra­molecular layers, forming a three-dimensional supra­molecular network.
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spelling pubmed-32008822011-11-06 Aqua­[4-(hy­droxy­imino­meth­yl)pyridine-κN (1)](imino­diacetato-κ(3) O,N,O′)copper(II) Yang, Yisheng Chai, Wenxiang Song, Li Yang, Yunyun Chen, Jiongke Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Cu(C(4)H(5)NO(4))(C(6)H(6)N(2)O)(H(2)O)], conventionally abbreviated Cu(IDA)(4-OXPy)(H(2)O), where IDA is imino­diacetate and 4-OXPy is 4-(hy­droxy­imino­meth­yl)pyridine, the Cu(II) atom exhibits a distorted square-pyramidal coordination geometry, which is constructed from two O atoms and one N atom from a IDA ligand, one N atom from 4-OXPy ligand and one O atom from water. This mol­ecule looks like a space shuttle, the IDA ligand is its empennage (tail), and the 4-OXPy ligand is its airframe. The complexes are linked into two-dimensional supra­molecular layers parallel to (100) by three pairs of O—H⋯O hydrogen bonds. Two pairs of N—H⋯O hydrogen bonds further connect these supra­molecular layers, forming a three-dimensional supra­molecular network. International Union of Crystallography 2011-08-27 /pmc/articles/PMC3200882/ /pubmed/22065407 http://dx.doi.org/10.1107/S1600536811033459 Text en © Yang et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Yang, Yisheng
Chai, Wenxiang
Song, Li
Yang, Yunyun
Chen, Jiongke
Aqua­[4-(hy­droxy­imino­meth­yl)pyridine-κN (1)](imino­diacetato-κ(3) O,N,O′)copper(II)
title Aqua­[4-(hy­droxy­imino­meth­yl)pyridine-κN (1)](imino­diacetato-κ(3) O,N,O′)copper(II)
title_full Aqua­[4-(hy­droxy­imino­meth­yl)pyridine-κN (1)](imino­diacetato-κ(3) O,N,O′)copper(II)
title_fullStr Aqua­[4-(hy­droxy­imino­meth­yl)pyridine-κN (1)](imino­diacetato-κ(3) O,N,O′)copper(II)
title_full_unstemmed Aqua­[4-(hy­droxy­imino­meth­yl)pyridine-κN (1)](imino­diacetato-κ(3) O,N,O′)copper(II)
title_short Aqua­[4-(hy­droxy­imino­meth­yl)pyridine-κN (1)](imino­diacetato-κ(3) O,N,O′)copper(II)
title_sort aqua­[4-(hy­droxy­imino­meth­yl)pyridine-κn (1)](imino­diacetato-κ(3) o,n,o′)copper(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200882/
https://www.ncbi.nlm.nih.gov/pubmed/22065407
http://dx.doi.org/10.1107/S1600536811033459
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