2-[(E)-(6-Amino-1,3-dimethyl-2,4-dioxo-1,2,3,4-tetra­hydro­pyrimidin-5-yl)imino­meth­yl]pyridinium bromide

The title compound, C(12)H(14)N(5)O(2) (+)·Br(−), is the hydro­bromide salt of a Schiff base in which protonation has taken place at the pyridine N atom. This organic cation is essentially planar (r.m.s. of all fitted non-H atoms = 0.0448 Å). In the crystal, N—H⋯Br hydrogen bonds as well as C—H⋯O an...

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Detalles Bibliográficos
Autores principales: Booysen, Irvin, Ismail, Muhammed, Gerber, Thomas, Hosten, Eric, Betz, Richard
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200889/
https://www.ncbi.nlm.nih.gov/pubmed/22065608
http://dx.doi.org/10.1107/S1600536811033290
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author Booysen, Irvin
Ismail, Muhammed
Gerber, Thomas
Hosten, Eric
Betz, Richard
author_facet Booysen, Irvin
Ismail, Muhammed
Gerber, Thomas
Hosten, Eric
Betz, Richard
author_sort Booysen, Irvin
collection PubMed
description The title compound, C(12)H(14)N(5)O(2) (+)·Br(−), is the hydro­bromide salt of a Schiff base in which protonation has taken place at the pyridine N atom. This organic cation is essentially planar (r.m.s. of all fitted non-H atoms = 0.0448 Å). In the crystal, N—H⋯Br hydrogen bonds as well as C—H⋯O and C–H⋯Br inter­actions connect the mol­ecules, forming a three-dimensional network.
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spelling pubmed-32008892011-11-06 2-[(E)-(6-Amino-1,3-dimethyl-2,4-dioxo-1,2,3,4-tetra­hydro­pyrimidin-5-yl)imino­meth­yl]pyridinium bromide Booysen, Irvin Ismail, Muhammed Gerber, Thomas Hosten, Eric Betz, Richard Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(12)H(14)N(5)O(2) (+)·Br(−), is the hydro­bromide salt of a Schiff base in which protonation has taken place at the pyridine N atom. This organic cation is essentially planar (r.m.s. of all fitted non-H atoms = 0.0448 Å). In the crystal, N—H⋯Br hydrogen bonds as well as C—H⋯O and C–H⋯Br inter­actions connect the mol­ecules, forming a three-dimensional network. International Union of Crystallography 2011-08-27 /pmc/articles/PMC3200889/ /pubmed/22065608 http://dx.doi.org/10.1107/S1600536811033290 Text en © Booysen et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Booysen, Irvin
Ismail, Muhammed
Gerber, Thomas
Hosten, Eric
Betz, Richard
2-[(E)-(6-Amino-1,3-dimethyl-2,4-dioxo-1,2,3,4-tetra­hydro­pyrimidin-5-yl)imino­meth­yl]pyridinium bromide
title 2-[(E)-(6-Amino-1,3-dimethyl-2,4-dioxo-1,2,3,4-tetra­hydro­pyrimidin-5-yl)imino­meth­yl]pyridinium bromide
title_full 2-[(E)-(6-Amino-1,3-dimethyl-2,4-dioxo-1,2,3,4-tetra­hydro­pyrimidin-5-yl)imino­meth­yl]pyridinium bromide
title_fullStr 2-[(E)-(6-Amino-1,3-dimethyl-2,4-dioxo-1,2,3,4-tetra­hydro­pyrimidin-5-yl)imino­meth­yl]pyridinium bromide
title_full_unstemmed 2-[(E)-(6-Amino-1,3-dimethyl-2,4-dioxo-1,2,3,4-tetra­hydro­pyrimidin-5-yl)imino­meth­yl]pyridinium bromide
title_short 2-[(E)-(6-Amino-1,3-dimethyl-2,4-dioxo-1,2,3,4-tetra­hydro­pyrimidin-5-yl)imino­meth­yl]pyridinium bromide
title_sort 2-[(e)-(6-amino-1,3-dimethyl-2,4-dioxo-1,2,3,4-tetra­hydro­pyrimidin-5-yl)imino­meth­yl]pyridinium bromide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200889/
https://www.ncbi.nlm.nih.gov/pubmed/22065608
http://dx.doi.org/10.1107/S1600536811033290
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