8-Hy­droxy-2-methyl­quinolinium dibromido(2-methyl­quinolin-8-olato-κ(2) N,O)zincate acetonitrile mono­solvate

The reaction of 2-methyl-8-hy­droxy­quinoline and zinc bromide in acetonitrile affords the title solvated salt, (C(10)H(10)NO)[ZnBr(2)(C(10)H(8)NO)]·CH(3)CN, in which the Zn(II) ion is coordinated by a N,O-chelating 2-methyl­quinolin-8-olate ligand and two bromide ligands in a distorted tetra­hedral...

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Detalles Bibliográficos
Autores principales: Najafi, Ezzatollah, Amini, Mostafa M., Ng, Seik Weng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200891/
https://www.ncbi.nlm.nih.gov/pubmed/22058877
http://dx.doi.org/10.1107/S160053681103234X
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author Najafi, Ezzatollah
Amini, Mostafa M.
Ng, Seik Weng
author_facet Najafi, Ezzatollah
Amini, Mostafa M.
Ng, Seik Weng
author_sort Najafi, Ezzatollah
collection PubMed
description The reaction of 2-methyl-8-hy­droxy­quinoline and zinc bromide in acetonitrile affords the title solvated salt, (C(10)H(10)NO)[ZnBr(2)(C(10)H(8)NO)]·CH(3)CN, in which the Zn(II) ion is coordinated by a N,O-chelating 2-methyl­quinolin-8-olate ligand and two bromide ligands in a distorted tetra­hedral geometry. The cation is linked to the anion by an O—H⋯O hydrogen bond and the quinolinium H atom forms an inter­molecular N—H⋯N hydrogen bond with the acetonitrile solvent mol­ecule.
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spelling pubmed-32008912011-11-06 8-Hy­droxy-2-methyl­quinolinium dibromido(2-methyl­quinolin-8-olato-κ(2) N,O)zincate acetonitrile mono­solvate Najafi, Ezzatollah Amini, Mostafa M. Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The reaction of 2-methyl-8-hy­droxy­quinoline and zinc bromide in acetonitrile affords the title solvated salt, (C(10)H(10)NO)[ZnBr(2)(C(10)H(8)NO)]·CH(3)CN, in which the Zn(II) ion is coordinated by a N,O-chelating 2-methyl­quinolin-8-olate ligand and two bromide ligands in a distorted tetra­hedral geometry. The cation is linked to the anion by an O—H⋯O hydrogen bond and the quinolinium H atom forms an inter­molecular N—H⋯N hydrogen bond with the acetonitrile solvent mol­ecule. International Union of Crystallography 2011-08-27 /pmc/articles/PMC3200891/ /pubmed/22058877 http://dx.doi.org/10.1107/S160053681103234X Text en © Najafi et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Najafi, Ezzatollah
Amini, Mostafa M.
Ng, Seik Weng
8-Hy­droxy-2-methyl­quinolinium dibromido(2-methyl­quinolin-8-olato-κ(2) N,O)zincate acetonitrile mono­solvate
title 8-Hy­droxy-2-methyl­quinolinium dibromido(2-methyl­quinolin-8-olato-κ(2) N,O)zincate acetonitrile mono­solvate
title_full 8-Hy­droxy-2-methyl­quinolinium dibromido(2-methyl­quinolin-8-olato-κ(2) N,O)zincate acetonitrile mono­solvate
title_fullStr 8-Hy­droxy-2-methyl­quinolinium dibromido(2-methyl­quinolin-8-olato-κ(2) N,O)zincate acetonitrile mono­solvate
title_full_unstemmed 8-Hy­droxy-2-methyl­quinolinium dibromido(2-methyl­quinolin-8-olato-κ(2) N,O)zincate acetonitrile mono­solvate
title_short 8-Hy­droxy-2-methyl­quinolinium dibromido(2-methyl­quinolin-8-olato-κ(2) N,O)zincate acetonitrile mono­solvate
title_sort 8-hy­droxy-2-methyl­quinolinium dibromido(2-methyl­quinolin-8-olato-κ(2) n,o)zincate acetonitrile mono­solvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200891/
https://www.ncbi.nlm.nih.gov/pubmed/22058877
http://dx.doi.org/10.1107/S160053681103234X
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AT ngseikweng 8hydroxy2methylquinoliniumdibromido2methylquinolin8olatok2nozincateacetonitrilemonosolvate

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