Bis­(chloro­acetato-κO)bis(trimethyl­silylmethyl)tin(IV)

In the title complex, [Sn(C(2)H(2)ClO(2))(2)(C(4)H(11)Si)(2)], the Sn(IV) ion is coordinated in a distorted tetra­hedral environment formed by two O atoms from two monodenate chloro­acetato ligands and two C atoms from two trimethyl silyl ligands. Two further weak intra­molecular Sn⋯O contacts [2.74...

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Detalles Bibliográficos
Autores principales: Ding, Rui-Fang, Wang, Qi-Bao
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200893/
https://www.ncbi.nlm.nih.gov/pubmed/22058841
http://dx.doi.org/10.1107/S1600536811028649
Descripción
Sumario:In the title complex, [Sn(C(2)H(2)ClO(2))(2)(C(4)H(11)Si)(2)], the Sn(IV) ion is coordinated in a distorted tetra­hedral environment formed by two O atoms from two monodenate chloro­acetato ligands and two C atoms from two trimethyl silyl ligands. Two further weak intra­molecular Sn⋯O contacts [2.744 (2) and 2.655 (2) Å] are formed by the chloro­acetato ligands.

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