Benzyl (E)-3-(2-methyl­benzyl­idene)dithio­carbazate

The title compound, C(16)H(16)N(2)S(2), was obtained from the condensation reaction of benzyl dithio­carbazate and 2-methyl­benzaldehyde. The asymmetric unit contains two independent mol­ecules. In both mol­ecules, the methyl­phenyl ring and the dithio­carbazate fragment are located on opposite sides of the C=N bond, showing an E conformation. In each mol­ecule, the dithio­carbazate fragment is approximately planar, the r.m.s deviations being 0.018 and 0.025 Å. The mean plane of dithio­carbazate group is oriented at dihedral angles of 7.9 (3) and 68.24 (12)°, respectively, to the methyl­phenyl and phenyl rings in one mol­ecule, while the corresponding angles in the other mol­ecule are 10.9 (3) and 69.76 (16)°. Inter­molecular N—H⋯S hydrogen bonding occurs in the crystal structure to generate inversion dimers for both molecules.