Bis[N-cyclohexyl-1-(2-{1-[(cyclohexyl­amino)carbonyl]cyclohexyl}-3,5-dioxo-1,2-oxazolidin-4-yl)cyclopentanecarbox­amide] monohydrate

The reaction of cyclo­hexyl isocyanide and alkyl­idene Meldrum’s acid (systematic name 2,2-dimethyl-1,3-dioxane-4,6-dione) in the presence of cyclo­hexyl ketoxime and dichloro­methane as solvent resulted in the title compound, 2C(28)H(43)N(3)O(5)·H(2)O. One methyl­ene group of the cyclo­pentane ring...

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Detalles Bibliográficos
Autores principales: Sheikhhosseini, Enayatollah, Vafadarnejad, Fahime, Habibi, Azizollah
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200895/
https://www.ncbi.nlm.nih.gov/pubmed/22058907
http://dx.doi.org/10.1107/S1600536811028868
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author Sheikhhosseini, Enayatollah
Vafadarnejad, Fahime
Habibi, Azizollah
author_facet Sheikhhosseini, Enayatollah
Vafadarnejad, Fahime
Habibi, Azizollah
author_sort Sheikhhosseini, Enayatollah
collection PubMed
description The reaction of cyclo­hexyl isocyanide and alkyl­idene Meldrum’s acid (systematic name 2,2-dimethyl-1,3-dioxane-4,6-dione) in the presence of cyclo­hexyl ketoxime and dichloro­methane as solvent resulted in the title compound, 2C(28)H(43)N(3)O(5)·H(2)O. One methyl­ene group of the cyclo­pentane ring was found to be disordered and was refined with occupancies 0.75:0.25. Intra­molecular N—H⋯O hydrogen bonds occur. The crystal structure is stabilized by inter­molecular N—H⋯O and O—H⋯O hydrogen bonds.
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spelling pubmed-32008952011-11-06 Bis[N-cyclohexyl-1-(2-{1-[(cyclohexyl­amino)carbonyl]cyclohexyl}-3,5-dioxo-1,2-oxazolidin-4-yl)cyclopentanecarbox­amide] monohydrate Sheikhhosseini, Enayatollah Vafadarnejad, Fahime Habibi, Azizollah Acta Crystallogr Sect E Struct Rep Online Organic Papers The reaction of cyclo­hexyl isocyanide and alkyl­idene Meldrum’s acid (systematic name 2,2-dimethyl-1,3-dioxane-4,6-dione) in the presence of cyclo­hexyl ketoxime and dichloro­methane as solvent resulted in the title compound, 2C(28)H(43)N(3)O(5)·H(2)O. One methyl­ene group of the cyclo­pentane ring was found to be disordered and was refined with occupancies 0.75:0.25. Intra­molecular N—H⋯O hydrogen bonds occur. The crystal structure is stabilized by inter­molecular N—H⋯O and O—H⋯O hydrogen bonds. International Union of Crystallography 2011-08-02 /pmc/articles/PMC3200895/ /pubmed/22058907 http://dx.doi.org/10.1107/S1600536811028868 Text en © Sheikhhosseini et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Sheikhhosseini, Enayatollah
Vafadarnejad, Fahime
Habibi, Azizollah
Bis[N-cyclohexyl-1-(2-{1-[(cyclohexyl­amino)carbonyl]cyclohexyl}-3,5-dioxo-1,2-oxazolidin-4-yl)cyclopentanecarbox­amide] monohydrate
title Bis[N-cyclohexyl-1-(2-{1-[(cyclohexyl­amino)carbonyl]cyclohexyl}-3,5-dioxo-1,2-oxazolidin-4-yl)cyclopentanecarbox­amide] monohydrate
title_full Bis[N-cyclohexyl-1-(2-{1-[(cyclohexyl­amino)carbonyl]cyclohexyl}-3,5-dioxo-1,2-oxazolidin-4-yl)cyclopentanecarbox­amide] monohydrate
title_fullStr Bis[N-cyclohexyl-1-(2-{1-[(cyclohexyl­amino)carbonyl]cyclohexyl}-3,5-dioxo-1,2-oxazolidin-4-yl)cyclopentanecarbox­amide] monohydrate
title_full_unstemmed Bis[N-cyclohexyl-1-(2-{1-[(cyclohexyl­amino)carbonyl]cyclohexyl}-3,5-dioxo-1,2-oxazolidin-4-yl)cyclopentanecarbox­amide] monohydrate
title_short Bis[N-cyclohexyl-1-(2-{1-[(cyclohexyl­amino)carbonyl]cyclohexyl}-3,5-dioxo-1,2-oxazolidin-4-yl)cyclopentanecarbox­amide] monohydrate
title_sort bis[n-cyclohexyl-1-(2-{1-[(cyclohexyl­amino)carbonyl]cyclohexyl}-3,5-dioxo-1,2-oxazolidin-4-yl)cyclopentanecarbox­amide] monohydrate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200895/
https://www.ncbi.nlm.nih.gov/pubmed/22058907
http://dx.doi.org/10.1107/S1600536811028868
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AT vafadarnejadfahime bisncyclohexyl121cyclohexylaminocarbonylcyclohexyl35dioxo12oxazolidin4ylcyclopentanecarboxamidemonohydrate
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