Tetra­kis(μ-2-phen­oxy­propionato)-κ(3) O,O′:O′;κ(3) O:O,O′,κ(4) O:O′-bis­[(1,10-phenanthroline-κ(2) N,N′)(2-phen­oxy­propionato-κ(2) O,O′)dysprosium(III)]

In the centrosymmetric binuclear title complex, [Dy(2)(C(9)H(9)O(3))(6)(C(12)H(8)N(2))(2)], the two Dy(III) ions are linked by four 2-phen­oxy­propionate (L) groups through their bi- and tridentate bridging modes. Each Dy(III) ion is nine-coordinated by one 1,10-phenanthroline mol­ecule, one bidenta...

Descripción completa

Detalles Bibliográficos
Autores principales: Shen, Jin-Bei, Liu, Jia-Lu, Zhao, Guo-Liang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200901/
https://www.ncbi.nlm.nih.gov/pubmed/22058895
http://dx.doi.org/10.1107/S1600536811034696
Descripción
Sumario:In the centrosymmetric binuclear title complex, [Dy(2)(C(9)H(9)O(3))(6)(C(12)H(8)N(2))(2)], the two Dy(III) ions are linked by four 2-phen­oxy­propionate (L) groups through their bi- and tridentate bridging modes. Each Dy(III) ion is nine-coordinated by one 1,10-phenanthroline mol­ecule, one bidentate carboxyl­ate group and four bridging carboxyl­ate groups in a distorted DyN(2)O(7) monocapped square-anti­prismatic geometry. The title compound is isotypic with its terbium-containing analogue.

Ejemplares similares