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Tetra­kis(μ-2-phen­oxy­propionato)-κ(3) O,O′:O′;κ(3) O:O,O′,κ(4) O:O′-bis­[(1,10-phenanthroline-κ(2) N,N′)(2-phen­oxy­propionato-κ(2) O,O′)dysprosium(III)]

In the centrosymmetric binuclear title complex, [Dy(2)(C(9)H(9)O(3))(6)(C(12)H(8)N(2))(2)], the two Dy(III) ions are linked by four 2-phen­oxy­propionate (L) groups through their bi- and tridentate bridging modes. Each Dy(III) ion is nine-coordinated by one 1,10-phenanthroline mol­ecule, one bidenta...

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Detalles Bibliográficos
Autores principales: Shen, Jin-Bei, Liu, Jia-Lu, Zhao, Guo-Liang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200901/
https://www.ncbi.nlm.nih.gov/pubmed/22058895
http://dx.doi.org/10.1107/S1600536811034696
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author Shen, Jin-Bei
Liu, Jia-Lu
Zhao, Guo-Liang
author_facet Shen, Jin-Bei
Liu, Jia-Lu
Zhao, Guo-Liang
author_sort Shen, Jin-Bei
collection PubMed
description In the centrosymmetric binuclear title complex, [Dy(2)(C(9)H(9)O(3))(6)(C(12)H(8)N(2))(2)], the two Dy(III) ions are linked by four 2-phen­oxy­propionate (L) groups through their bi- and tridentate bridging modes. Each Dy(III) ion is nine-coordinated by one 1,10-phenanthroline mol­ecule, one bidentate carboxyl­ate group and four bridging carboxyl­ate groups in a distorted DyN(2)O(7) monocapped square-anti­prismatic geometry. The title compound is isotypic with its terbium-containing analogue.
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spelling pubmed-32009012011-11-06 Tetra­kis(μ-2-phen­oxy­propionato)-κ(3) O,O′:O′;κ(3) O:O,O′,κ(4) O:O′-bis­[(1,10-phenanthroline-κ(2) N,N′)(2-phen­oxy­propionato-κ(2) O,O′)dysprosium(III)] Shen, Jin-Bei Liu, Jia-Lu Zhao, Guo-Liang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the centrosymmetric binuclear title complex, [Dy(2)(C(9)H(9)O(3))(6)(C(12)H(8)N(2))(2)], the two Dy(III) ions are linked by four 2-phen­oxy­propionate (L) groups through their bi- and tridentate bridging modes. Each Dy(III) ion is nine-coordinated by one 1,10-phenanthroline mol­ecule, one bidentate carboxyl­ate group and four bridging carboxyl­ate groups in a distorted DyN(2)O(7) monocapped square-anti­prismatic geometry. The title compound is isotypic with its terbium-containing analogue. International Union of Crystallography 2011-08-31 /pmc/articles/PMC3200901/ /pubmed/22058895 http://dx.doi.org/10.1107/S1600536811034696 Text en © Shen et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Shen, Jin-Bei
Liu, Jia-Lu
Zhao, Guo-Liang
Tetra­kis(μ-2-phen­oxy­propionato)-κ(3) O,O′:O′;κ(3) O:O,O′,κ(4) O:O′-bis­[(1,10-phenanthroline-κ(2) N,N′)(2-phen­oxy­propionato-κ(2) O,O′)dysprosium(III)]
title Tetra­kis(μ-2-phen­oxy­propionato)-κ(3) O,O′:O′;κ(3) O:O,O′,κ(4) O:O′-bis­[(1,10-phenanthroline-κ(2) N,N′)(2-phen­oxy­propionato-κ(2) O,O′)dysprosium(III)]
title_full Tetra­kis(μ-2-phen­oxy­propionato)-κ(3) O,O′:O′;κ(3) O:O,O′,κ(4) O:O′-bis­[(1,10-phenanthroline-κ(2) N,N′)(2-phen­oxy­propionato-κ(2) O,O′)dysprosium(III)]
title_fullStr Tetra­kis(μ-2-phen­oxy­propionato)-κ(3) O,O′:O′;κ(3) O:O,O′,κ(4) O:O′-bis­[(1,10-phenanthroline-κ(2) N,N′)(2-phen­oxy­propionato-κ(2) O,O′)dysprosium(III)]
title_full_unstemmed Tetra­kis(μ-2-phen­oxy­propionato)-κ(3) O,O′:O′;κ(3) O:O,O′,κ(4) O:O′-bis­[(1,10-phenanthroline-κ(2) N,N′)(2-phen­oxy­propionato-κ(2) O,O′)dysprosium(III)]
title_short Tetra­kis(μ-2-phen­oxy­propionato)-κ(3) O,O′:O′;κ(3) O:O,O′,κ(4) O:O′-bis­[(1,10-phenanthroline-κ(2) N,N′)(2-phen­oxy­propionato-κ(2) O,O′)dysprosium(III)]
title_sort tetra­kis(μ-2-phen­oxy­propionato)-κ(3) o,o′:o′;κ(3) o:o,o′,κ(4) o:o′-bis­[(1,10-phenanthroline-κ(2) n,n′)(2-phen­oxy­propionato-κ(2) o,o′)dysprosium(iii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200901/
https://www.ncbi.nlm.nih.gov/pubmed/22058895
http://dx.doi.org/10.1107/S1600536811034696
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