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(4,5-Diazafluoren-9-one-κ(2) N,N′)bis(1H-imidazole-κN (3))bis(thiocyanato-κN)cobalt(II)
In the title complex, [Co(NCS)(2)(C(3)H(4)N(2))(2)(C(11)H(6)N(2)O)], the Co(II) atom has a distorted octahedral coordination with the N atoms of the 4,5-diazafluoren-9-one ligand and two N atoms from imidazole ligands in the equatorial positions and the axial sites occupied by two N atoms of the t...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2011
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3200902/ https://www.ncbi.nlm.nih.gov/pubmed/22058833 http://dx.doi.org/10.1107/S1600536811029060 |
| Sumario: | In the title complex, [Co(NCS)(2)(C(3)H(4)N(2))(2)(C(11)H(6)N(2)O)], the Co(II) atom has a distorted octahedral coordination with the N atoms of the 4,5-diazafluoren-9-one ligand and two N atoms from imidazole ligands in the equatorial positions and the axial sites occupied by two N atoms of the thiocyanate ligand. Intermolecular N—H⋯O hydrogen bonding forms a one-dimensional motif parallel to the cell ab diagonal. |
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